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http://dx.doi.org/10.18419/opus-14308
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DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Conrad, Maurice | - |
dc.contributor.author | Russ, Philip L. | - |
dc.contributor.author | Schleid, Thomas | - |
dc.date.accessioned | 2024-04-30T13:41:35Z | - |
dc.date.available | 2024-04-30T13:41:35Z | - |
dc.date.issued | 2020 | de |
dc.identifier.issn | 1521-3749 | - |
dc.identifier.issn | 0044-2313 | - |
dc.identifier.other | 1887883533 | - |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-143271 | de |
dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/14327 | - |
dc.identifier.uri | http://dx.doi.org/10.18419/opus-14308 | - |
dc.description.abstract | Colorless single crystals of Sr[ReO4]2 were obtained from halide melts at 1123 K in open corundum crucibles. X‐ray diffraction revealed that Sr[ReO4]2 crystallizes in the monoclinic space group P21/n with the lattice parameters a = 627.31(4) pm, b = 1004.56(7) pm, c = 1271.25(9) pm and β = 97.118(3)° for Z = 4. The crystal structure contains a unique Sr2+‐cation site surrounded by eight crystallographically different oxygen atoms forming distorted bicapped trigonal prisms. All corners of these [SrO8]14- polyhedra (d(Sr-O) = 259-268 pm) are shared with tetrahedral meta‐perrhenate units [ReO4]- (d(Re-O) = 166-173 pm) formed from two crystallographically different Re7+ cations surrounded by four O2- anions each, building up the three‐dimensional mosaic‐like structure of Sr[ReO4]2. Single‐crystal Raman data confirm the presence of two different kinds of symmetry‐free meta‐perrhenate units [ReO4]- and match well with results known from literature. | en |
dc.description.sponsorship | Federal State of Baden-Württemberg | de |
dc.description.sponsorship | Projekt DEAL | de |
dc.language.iso | en | de |
dc.relation.uri | doi:10.1002/zaac.202000312 | de |
dc.rights | info:eu-repo/semantics/openAccess | de |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | de |
dc.subject.ddc | 540 | de |
dc.title | Sr[ReO4]2 : the first single crystals of an anhydrous alkaline‐earth metal meta‐perrhenate | en |
dc.type | article | de |
dc.date.updated | 2023-11-14T05:07:22Z | - |
ubs.fakultaet | Chemie | de |
ubs.institut | Institut für Anorganische Chemie | de |
ubs.publikation.seiten | 1872-1875 | de |
ubs.publikation.source | Zeitschrift für anorganische und allgemeine Chemie 646 (2020), S. 1872-1875 | de |
ubs.publikation.typ | Zeitschriftenartikel | de |
Enthalten in den Sammlungen: | 03 Fakultät Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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ZAAC_ZAAC202000312.pdf | 640,07 kB | Adobe PDF | Öffnen/Anzeigen |
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