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Bromide and iodide perovskites, especially their mixtures, hold great potential for opto-electronic application due to their optical absorption properties in the visible range. While it is established that these materials are mixed ionic-electronic conductors, their ionic transport properties both in&...
Diese Arbeit beschreibt die Synthese und Charakterisierung von stickstoffhaltigen Liganden mit Phosphonat-Ankergruppen, die Immobilisierung ihrer Kupferkomplexe auf oxidischen Trägermaterialien, sowie den Einsatz dieser immobilisierten Komplexe als Katalysatoren für Atomtransfer-Radikaladditionsreaktionen.
This study focuses on the contexts of language experience in relation to language dominance in eighty-seven Italian-German primary school children in Germany using the MAIN narrative task. We compare current language experience in the heritage language (Italian) and the majority language (Ge...
Friction stir welding, as a solid-state welding technique, is especially suitable for effectively joining high-strength aluminum alloys, as well as for multi-material welds. This research investigates the friction stir welding of thin aluminum and steel sheets, an essential process in the pr...
To efficiently mitigate the reversible performance degradation of polymer electrolyte membrane fuel cells, it is crucial to thoroughly understand recovery effects. In this work, the effect of operando performance recovery by temperature reduction is evaluated. The results reveal that operando red...
Revolutionary and cost-effective state estimation techniques are crucial for advancing lithium-ion battery technology, especially in mobile applications. Accurate prediction of battery state-of-health (SoH) enhances state-of-charge estimation while providing valuable insights into performance, second-life utility, and sa...
N-Körper Beschleunigungsberechnungen werden in diversen Bereichen der Wissenschaft durchgeführt, zum Beispiel bei der Simulation von Sonnensystemen in der Astronomie oder auch beim Simulieren von Teilchensystemen im Molekularbereich. Da diese Simulationen eine große Anzahl an Körpern enthalten können, gibt ...
Functionalized nanogaps embedded in nanopores show a strong potential for enhancing the detection of biomolecules, their length, type, and sequence. This detection is strongly dependent on the features of the target biomolecules, as well as the characteristics of the sensing device. In ...
Metalation of secondary diaminophosphine boranes by alkali metal amides provides a robust and selective access route to a range of metal diaminophosphide boranes M[(R2N)2P(BH3)] (M=Li, Na, K; R=alkyl, aryl) with acyclic or heterocyclic molecular backbones, whereas reduction of a chlorodiaminophosphine...
A diphosphine with an unsupported PP bond connecting two carbon‐free “inorganic” 1,3,2,4,5‐diazaphosphadisilolidine rings was prepared by reductive coupling of a P‐chloro‐substituted monocyclic precursor molecule. VT‐EPR studies revealed that the diphosphine exists in solution, like other compounds of this ...
The instrument package SEIS (Seismic Experiment for Internal Structure) with the three very broadband and three short‐period seismic sensors is installed on the surface on Mars as part of NASA's InSight Discovery mission. When compared to terrestrial installations, SEIS is deployed in...
How hypertonic stress induces or sensitizes to cell death signals is incompletely understood and rarely studied in cancer. Heimer et al. demonstrate that hypertonic environments neutralize the antiapoptotic Bcl‐2 family member Mcl‐1 by upregulating its antagonist Noxa. Consequently, hypertonically str...
Hybrid materials consisting of organic semiconductors and molecular quantum bits promise to provide a novel platform for quantum spintronic applications. However, investigations of such materials, elucidating both the electrical and quantum dynamical properties of the same material have never been...
The europium(II) oxoborate Li2Eu3Br2[BO3]2 featuring lithium and bromide ions was synthesized by the reaction of Eu2O3 with Li[BH4] as lithium‐ and boron‐ as well as EuBr3 as bromide‐source at 750 °C for 24 h in silica‐jacketed sealed niobium capsules. The yellow, air‐stable and ye...
A structural evaluation is imperative for developing an effective virtual learning environment. Understanding the extent to which content that has been learned virtually can be applied practically holds particular importance. A group of persons from the technical field of mechanical and plan...
Spatial confinement effects on hindered transport in mesoporous silica particles are quantified using reconstructions of their morphology obtained by electron tomography as geometrical models in direct diffusion simulations for passive, finite‐size tracers. We monitor accessible porosity and effective diff...
Amorpha‐4,11‐diene (AMD4,11) is a precursor to artemisinin, a potent antimalarial drug that is traditionally extracted from the shrubs of Artemisia annua. Despite significant prior efforts to produce artemisinin and its precursors through biotechnology, there remains a dire need for more efficien...
Chickpea (Cicer arietinum) allergy has frequently been reported particularly in Spain and India. Nevertheless, chickpea allergens are poorly characterized. The authors aim to identify and characterize potential allergens from chickpea. Candidate proteins are selected by an in silico approach or i...
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