Browsing by Author "Nixon, John F."

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Open Access
First examples of η1-ligated halogenophosphaalkenes - crystal structures of trans-[RhCl(PPh3)2{η1-PX=C(SiMe3)2}] (X = F or Cl)
(1989) Hitchcock, Peter B.; Meidine, Mohamed F.; Nixon, John F.; Wang, Hongrui; Gudat, Dietrich; Niecke, Edgar
Syntheses and single crystal X-ray diffraction studies of the η1-halogenophosphaalkene complexes trans-[RhCl(PPh3)2{η1-PX=C(SiMe3)2}] (X = F, Cl) are reported.
Open Access
Reaction of P-halogeno-phospha-alkenes with alkene complexes of nickel and platinum: η2-co-ordination and unusual oxidative addition behaviour
(1989) Gudat, Dietrich; Meidine, Mohamed F.; Nixon, John F.; Niecke, Edgar
Phospha-alkenes X-P=CTMS2(X = F, Cl, I; TMS = SiMe3) display different reaction behaviour towards metal complexes (Bu3P)2Ni(cod)(cod = cyclo-octa-1,5-diene) or (Ph3P)2Pt(C2H4), respectively, undergoing either co-ordination to give η2-phospha-alkene complexes or alternatively oxidative addition of the P-X bond, forming phospha-alkenyl-metal(II) complexes, [(R3P)2M(X)(σ-P=CTMS2)].