Browsing by Author "Untereiner, Gabriele"

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Open Access
Characterization of harmonic modes and parasitic resonances in multi-mode superconducting coplanar resonators
(2023) Beydeda, Cenk; Nikolaou, Konstantin; Tochtermann, Marius; Ebensperger, Nikolaj G.; Untereiner, Gabriele; Farag, Ahmed; Karl, Philipp; Ubl, Monika; Giessen, Harald; Dressel, Martin; Scheffler, Marc
Open Access
Charge-order phase transition in the quasi one-dimensional organic conductor (TMTTF)2NO3
(2020) Majer, Lena N.; Miksch, Björn; Lesseux, Guilherme Gorgen; Untereiner, Gabriele; Dressel, Martin
Low-dimensional organic conductors show a rich phase diagram, which has, despite all efforts, still some unexplored regions. Charge ordered phases present in many compounds of the (TMTTF)2X family are typically studied with their unique electronic properties in mind. An influence on the spin arrangement is, however, not expected at first glance. Here, we report temperature and angle dependent electron spin resonance (ESR) measurements on the quasi one-dimensional organic conductor (TMTTF)2NO3. We found that the (TMTTF)2NO3 compound develops a peculiar anisotropy with a doubled periodicity (ab′-plane) of the ESR linewidth below about TCO=(250±10) K. This behavior is similar to observations in the related compounds (TMTTF)2X (X=PF6, SbF6 and AsF6), where it has been attributed to relaxation processes of magnetically inequivalent sites in the charge-ordered state. For the structural analogous (TMTTF)2ClO4, known for the absence of charge order, such angular dependence of the ESR signal is not observed. Therefore, our ESR measurements lead us to conclude that a charge-order phase is stabilized in the title compound below TCO≈250 K.
Open Access
Tuning charge order in (TMTTF)2X by partial anion substitution
(2021) Pustogow, Andrej; Dizdarevic, Daniel; Erfort, Sebastian; Iakutkina, Olga; Merkl, Valentino; Untereiner, Gabriele; Dressel, Martin
In the quasi-one-dimensional (TMTTF)2X compounds with effectively quarter-filled bands, electronic charge order is stabilized from the delicate interplay of Coulomb repulsion and electronic bandwidth. The correlation strength is commonly tuned by physical pressure or chemical substitution with stoichiometric ratios of anions and cations. Here, we investigate the charge-ordered state through partial substitution of the anions in (TMTTF)2[AsF6]1-x[SbF6]x with x≈0.3, determined from the intensity of infrared vibrations, which is sufficient to suppress the spin-Peierls state. Our dc transport experiments reveal a transition temperature TCO = 120 K and charge gap ΔCO=430 K between the values of the two parent compounds (TMTTF)2AsF6 and (TMTTF)2SbF6. Upon plotting the two parameters for different (TMTTF)2X, we find a universal relationship between TCO and ΔCO yielding that the energy gap vanishes for transition temperatures TCO≤60 K. While these quantities indicate that the macroscopic correlation strength is continuously tuned, our vibrational spectroscopy results probing the local charge disproportionation suggest that 2δ is modulated on a microscopic level.