05 Fakultät Informatik, Elektrotechnik und Informationstechnik
Permanent URI for this collectionhttps://elib.uni-stuttgart.de/handle/11682/6
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Item Open Access Plasmonic gratings from highly doped Ge1-ySny films on Si(2021) Berkmann, Fritz; Ayasse, Markus; Schlipf, Jon; Mörz, Florian; Weißhaupt, David; Oehme, Michael; Prucnal, Slawomir; Kawaguchi, Yuma; Schwarz, Daniel; Fischer, Inga Anita; Schulze, JörgPlasmonic modes in metal structures are of great interest for optical applications. While metals such as Au and Ag are highly suitable for such applications at visible wavelengths, their high Drude losses limit their usefulness at mid-infrared wavelengths. Highly n-doped Ge1-ySny alloys are interesting possible alternative materials for plasmonic applications in this wavelength range. Here, we investigate the use of highly n-doped Ge1-ySny films grown directly on Si by molecular beam epitaxy with varying Sn-content from 0% up to 7.6% for plasmonic grating structures. We compare plasma wavelengths and relaxation times obtained from electrical and optical characterization. While theoretical considerations indicate that the decreasing effective mass with increasing Sn content in Ge1-ySny films could improve performance for plasmonic applications, our optical characterization results show that the utilization of Ge1-ySny films grown directly on Si is only beneficial if material quality can be improved.Item Open Access Top‐down approach to study chemical and electronic properties of perovskite solar cells : sputtered depth profiling versus tapered cross‐sectional photoelectron spectroscopies(2021) Das, Chittaranjan; Zia, Waqas; Mortan, Claudiu; Hussain, Navid; Saliba, Michael; Ingo Flege, Jan; Kot, MałgorzataA study of the chemical and electronic properties of various layers across perovskite solar cell (PSC) stacks is challenging. Depth‐profiling photoemission spectroscopy can be used to study the surface, interface, and bulk properties of different layers in PSCs, which influence the overall performance of these devices. Herein, sputter depth profiling (SDP) and tapered cross‐sectional (TCS) photoelectron spectroscopies (PESs) are used to study highly efficient mixed halide PSCs. It is found that the most used SDP‐PES technique degrades the organic and deforms the inorganic materials during sputtering of the PSCs while the TCS‐PES method is less destructive and can determine the chemical and electronic properties of all layers precisely. The SDP‐PES dissociates the chemical bonding in the spiro‐MeOTAD and perovskite layer and reduces the TiO2, which causes the chemical analysis to be unreliable. The TCS‐PES revealed a band bending only at the spiro‐MeOTAD/perovskite interface of about 0.7 eV. Both the TCS and SDP‐PES show that the perovskite layer is inhomogeneous and has a higher amount of bromine at the perovskite/TiO2 interface.Item Open Access Revealing the energy level and charge dynamics interplay in mixed Pb‐Sn perovskite solar cells with novel phenoxazine and phenothiazine self‐assembled monolayers(2025) Cuzzupè, Daniele T.; Franckevičius, Marius; Karalis, Orestis; Temitmie, Yekitwork Abebe; Marčinskas, Mantas; Azhar, Maria; Britto, Neethinathan Johnee; Eberle, Timo; Andrienko, Denis; Getautis, Vytautas; Malinauskas, Tadas; Hempel, Hannes; Schmidt‐Mende, LukasHole‐selective self‐assembled monolayers (SAMs) based on carbazole head groups have enabled major performance improvements of perovskite solar cells (PSCs) by eliminating parasitic absorption and nonradiative losses. However, the energy levels of the carbazole‐based, commercially available SAMs poorly match the valence band maximum (VBM) of narrow‐bandgap, lead‐tin (Pb‐Sn) perovskites, relevant for tandem applications. In this work, we expand the library of SAMs compatible with Pb‐Sn PSCs by synthesizing four novel SAMs containing phenoxazine (POz) and phenothiazine (PTz) as their head groups and investigate their interaction with the Pb‐Sn perovskite in detail. We obtain working devices with all SAMs, but despite significant differences between the highest occupied molecular orbital (HOMO) levels of the SAMs, the open‐circuit voltage (VOC) and fill factor (FF) across devices remains similar, suggesting that the role of energy level alignment is less relevant at this interface. Through in‐depth analysis including photoluminescence quantum yield (PLQY), transient photocurrent (TPC), and combined time‐resolved surface photovoltage (trSPV) and time‐resolved photoluminescence (trPL) measurements, we unveil the charge extraction dynamics of these systems featuring different head groups and HOMOs. This work highlights that the SAMs’ structure affects the overall charge extraction process and provides insights into the strategies needed to maximize charge extraction for more efficient PSCs.Item Open Access Uncertainty quantification and propagation in surrogate-based Bayesian inference(2025) Reiser, Philipp; Aguilar, Javier Enrique; Guthke, Anneli; Bürkner, Paul-ChristianSurrogate models are statistical or conceptual approximations for more complex simulation models. In this context, it is crucial to propagate the uncertainty induced by limited simulation budget and surrogate approximation error to predictions, inference, and subsequent decision-relevant quantities. However, quantifying and then propagating the uncertainty of surrogates is usually limited to special analytic cases or is otherwise computationally very expensive. In this paper, we propose a framework enabling a scalable, Bayesian approach to surrogate modeling with thorough uncertainty quantification, propagation, and validation. Specifically, we present three methods for Bayesian inference with surrogate models given measurement data. This is a task where the propagation of surrogate uncertainty is especially relevant, because failing to account for it may lead to biased and/or overconfident estimates of the parameters of interest. We showcase our approach in three detailed case studies for linear and nonlinear real-world modeling scenarios. Uncertainty propagation in surrogate models enables more reliable and safe approximation of expensive simulators and will therefore be useful in various fields of applications.Item Open Access Multi-material blind beam hardening correction in near real-time based on non-linearity adjustment of projections(2023) Alsaffar, Ammar; Sun, Kaicong; Simon, SvenBeam hardening (BH) is one of the major artifacts that severely reduces the quality of computed tomography (CT) imaging. This BH artifact arises due to the polychromatic nature of the X-ray source and causes cupping and streak artifacts. This work aims to propose a fast and accurate BH correction method that requires no prior knowledge of the materials and corrects first and higher-order BH artifacts. This is achieved by performing a wide sweep of the material based on an experimentally measured look-up table to obtain the closest estimate of the material. Then, the non-linearity effect of the BH is corrected by adding the difference between the estimated monochromatic and the polychromatic simulated projections of the segmented image. The estimated polychromatic projection is accurately derived using the least square estimation (LSE) method by minimizing the difference between the experimental projection and the linear combination of simulated polychromatic projections. As a result, an accurate non-linearity correction term is derived that leads to an accurate BH correction result. The simulated projections in this work are performed using a multi-GPU-accelerated forward projection model which ensures a fast BH correction in near real-time. To evaluate the proposed BH correction method, we have conducted extensive experiments on real-world CT data. It is shown that the proposed method results in images with improved contrast-to-noise ratio (CNR) in comparison to the images corrected from only the scatter artifacts and the BH-corrected images using the state-of-the-art empirical BH correction method.Item Open Access Sharp MIR plasmonic modes in gratings made of heavily doped pulsed laser-melted Ge1-xSnx(2023) Berkmann, Fritz; Steuer, Oliver; Ganss, Fabian; Prucnal, Slawomir; Schwarz, Daniel; Fischer, Inga Anita; Schulze, JörgItem Open Access Boron partitioning coefficient above unity in laser crystallized silicon(2017) Lill, Patrick C.; Dahlinger, Morris; Köhler, Jürgen R.Item Open Access Raman shifts in MBE‐grown SixGe1 - x - ySny alloys with large Si content(2021) Schlipf, Jon; Tetzner, Henriette; Spirito, Davide; Manganelli, Costanza L.; Capellini, Giovanni; Huang, Michael R. S.; Koch, Christoph T.; Clausen, Caterina J.; Elsayed, Ahmed; Oehme, Michael; Chiussi, Stefano; Schulze, Jörg; Fischer, Inga A.We examine the Raman shift in silicon-germanium-tin alloys with high silicon content grown on a germanium virtual substrate by molecular beam epitaxy. The Raman shifts of the three most prominent modes, Si-Si, Si-Ge, and Ge-Ge, are measured and compared with results in previous literature. We analyze and fit the dependence of the three modes on the composition and strain of the semiconductor alloys. We also demonstrate the calculation of the composition and strain of SixGe1 - x - ySny from the Raman shifts alone, based on the fitted relationships. Our analysis extends previous results to samples lattice matched on Ge and with higher Si content than in prior comprehensive Raman analyses, thus making Raman measurements as a local, fast, and nondestructive characterization technique accessible for a wider compositional range of these ternary alloys for silicon‐based photonic and microelectronic devices.Item Open Access Measurement of transient overvoltages by capacitive electric field sensors(2024) Probst, Felipe L.; Beltle, Michael; Tenbohlen, StefanThe accurate measurement and the investigation of electromagnetic transients are becoming more important, especially with the increasing integration of renewable energy sources into the power grid. These sources introduce new transient phenomena due to the extensive use of power electronics. To achieve this, the measurement devices must have a broadband response capable of measuring fast transients. This paper presents a capacitive electric field sensor-based measurement system to measure transient overvoltages in high-voltage substations. The concept and design of the measurement system are first presented. Then, the design and concept are validated using tests performed in a high-voltage laboratory. Afterwards, two different calibration techniques are discussed: the simplified method (SM) and the coupling capacitance compensation (CCC) method. Finally, three recorded transients are evaluated using the calibration methods. The investigation revealed that the SM tends to overestimate the maximum overvoltage, highlighting the CCC method as a more suitable approach for calibrating transient overvoltage measurements. This measurement system has been validated using various measurements and can be an efficient and flexible solution for the long-term monitoring of transient overvoltages in high-voltage substations.Item Open Access Multiplexed pseudo-deterministic photon source with asymmetric switching elements(2024) Brandhofer, Sebastian; Myers, Casey R.; Devitt, Simon; Polian, Ilia