Universität Stuttgart
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Item Open Access A fix that may fail : a qualitative model to explore potential rebound effects of digital textile microfactories(2024) Martinez‐Jaramillo, Juan Esteban; Tilebein, MeikeFast fashion principles and mass production within globalised supply chains are pivotal in driving the economic success of the fashion industry, but they also contribute significantly to its severe environmental impacts, which must be mitigated. Digital textile microfactories are innovative small‐scale fully digitalised design and manufacturing systems that present a promising technological solution. These offer the companies that adopt them environmental and economic advantages. However, their widespread adoption in the industry may have unintended consequences. This study hypothesises a rebound effect within the industry and proposes a qualitative modelling approach based on causal loop diagrams. We present a model for identifying rebound mechanisms that may accelerate purchases, along with a mitigation strategy emphasising the consideration of customer behaviour. The contribution of this paper is twofold: Firstly, it provides a starting point for detailed quantitative studies, and secondly, it offers insights for policy‐making towards a sustainable transition in the industry.Item Open Access Constitutive correlations for mass transport in fibrous media based on asymptotic homogenization(2023) Maier, Lukas; Kufferath-Sieberin, Lars; Pauly, Leon; Hopp-Hirschler, Manuel; Gresser, Götz T.; Nieken, UlrichMass transport in textiles is crucial. Knowledge of effective mass transport properties of textiles can be used to improve processes and applications where textiles are used. Mass transfer in knitted and woven fabrics strongly depends on the yarn used. In particular, the permeability and effective diffusion coefficient of yarns are of interest. Correlations are often used to estimate the mass transfer properties of yarns. These correlations commonly assume an ordered distribution, but here we demonstrate that an ordered distribution leads to an overestimation of mass transfer properties. We therefore address the impact of random ordering on the effective diffusivity and permeability of yarns and show that it is important to account for the random arrangement of fibers in order to predict mass transfer. To do this, Representative Volume Elements are randomly generated to represent the structure of yarns made from continuous filaments of synthetic materials. Furthermore, parallel, randomly arranged fibers with a circular cross-section are assumed. By solving the so-called cell problems on the Representative Volume Elements, transport coefficients can be calculated for given porosities. These transport coefficients, which are based on a digital reconstruction of the yarn and asymptotic homogenization, are then used to derive an improved correlation for the effective diffusivity and permeability as a function of porosity and fiber diameter. At porosities below 0.7, the predicted transport is significantly lower under the assumption of random ordering. The approach is not limited to circular fibers and may be extended to arbitrary fiber geometries.Item Open Access Polycondensation‐derived high‐molecular weight lignin as nonblended precursor for carbon fibers(2024) Clauss, Manuel M.; Frank, Erik; Bauch, Volker; Kuske, Lisa; Buchmeiser, Michael R.A new concept for the controlled chain‐extension of lignin has been developed. A mixture of trioxane as formaldehyde source, resorcinol as chain extender, and lignin allows to prepare high molecular weight precursor fibers by melt‐spinning, which can be spun on a semitechnical scale. Chain extension with resorcinol bridged by methylene groups is achieved during the stabilization process of the precursor fiber. After carbonization, carbon fibers (CFs) with an average diameter of 18 µm show an average tensile strength of 0.78 GPa and a Young's modulus of 106 GPa. A maximum tensile strength of 2.44 GPa and a Young's modulus of 294 GPa are reached with fibers 9.7 µm in diameter.Item Open Access Data processing, analysis, and evaluation methods for co-design of coreless filament-wound building systems(2023) Gil Pérez, Marta; Mindermann, Pascal; Zechmeister, Christoph; Forster, David; Guo, Yanan; Hügle, Sebastian; Kannenberg, Fabian; Balangé, Laura; Schwieger, Volker; Middendorf, Peter; Bischoff, Manfred; Menges, Achim; Gresser, Götz T.; Knippers, JanItem Open Access Modelling pore size distribution function of twist-texturized yarns and single-jersey knitted fabrics(2025) Pauly, Leon; Maier, Lukas; Schmied, Sibylle; Dinkelmann, Albrecht; Nieken, Ulrich; Gresser, Götz T.Pore sizes on the micrometre scale are a critical factor influencing the fluid transport properties of textiles. Consequently, the pore size distribution function is a desirable parameter in the design of textiles for technical applications. However, the experimental determination of pore size and its distribution can be challenging, costly, or impractical. Knitted fabrics offer a wide range of porosity and pore size distribution properties. While statistical models have shown reasonable accuracy in predicting pore size distributions in nonwovens and filter media, no equivalent model exists for twist-texturized yarns and single-jersey knitted fabrics. This study presents a hierarchical pore model for single-jersey fabrics. The model uses a log-normal distribution for the intra-yarn pores in the yarn and cylindrical pores for inter-yarn pores between the yarns in the fabric. With these two pore sizes, the model quantitatively characterises the porous structure of the fabric. Initial validation of the model for intra-yarn pores on four yarns of different fibre finenesses shows that the model can cover the influence of different fibre counts. For the validation on the fabric scale, two tomography datasets of single-jersey knitted fabrics show that the presented model can capture the effect of different fabric structures. A parameter study visualises the effects of both yarn and knitting parameters on the pore size distribution function of single-jersey knitted fabrics. The mean pore sizes of the fabrics are given. The results deepen the understanding of the porous properties of knitted fabrics and provide a valuable direction for structural fabric development on knitting machines.Item Open Access Chitin/cellulose blend fibers prepared by wet and dry‐wet spinning(2020) Ota, Antje; Beyer, Ronald; Hageroth, Ulrich; Müller, Alexandra; Tomasic, Patricija; Hermanutz, Frank; Buchmeiser, Michael R.We describe the wet and dry‐wet spinning of multifilament cellulosic composite fibers, namely chitin/cellulose fibers. The direct solution process for the two biopolymers based on an ionic liquid as solvent represents an environmentally friendly and alternative technology to the industrially applied viscose and lyocell process. Both cellulose and chitin possess good solubility in 1‐ethyl‐3‐methylimidazolium propionate ([C2C1Im][OPr]) and were spun into multifilament composite fibers. Moreover, for the first time, pure chitin multifilament fibers were obtained by dry‐wet spinning. The effect of chitin addition on the filament properties was investigated and evaluated by microscopic, spectroscopic, and mechanical analyses.Item Open Access Hydrosilylation of alkynes under continuous flow using polyurethane‐based monolithic supports with tailored mesoporosity(2022) Acikalin, Hande; Panyam, Pradeep K. R.; Shaikh, Abdul Wasif; Wang, Dongren; Kousik, Shravan R.; Atanasova, Petia; Buchmeiser, Michael R.Non‐porous polyurethane‐based monoliths are prepared under solvent‐induced phase separation conditions. They possess low specific surface areas of 0.15 m2 g-1, pore volumes of 1 µL g-1, and a non‐permanent, solvent‐induced microporosity with pore dimensions ≤1 nm. Mesoporosity can be introduced by varying the monomers and solvents. A tuning of the average solubility parameter of the solvent mixture by increasing the macroporogen content results in a decrease in the volume fraction of micropores from 70% to 40% and an increase in the volume fraction of pores in the range of 1.7-9.6 nm from 22% to 41% with only minor changes in the volume fraction of larger mesopores in the range of 9.6–50 nm. The polymeric monoliths are functionalized with quaternary ammonium groups, which allowed for the immobilization of an ionic liquid that contained the ionic Rh‐catalyst [1‐(pyrid‐2‐yl)‐3‐mesityl)‐imidazol‐2‐ylidene))(η4‐1,5‐cyclooctadiene)Rh(I) tetrafluoroborate]. The supported catalyst is used in the hydrosilylation of 1‐alkynes with dimethylphenylsilane under continuous flow using methyl‐tert‐butyl ether as second liquid transport phase. E/Z‐selectivity in hydrosilylation is compared to the one of the analogous biphasic reactions. The strong increase in Z‐selectivity is attributed to a confinement effect provided by the small mesopores.Item Open Access Melt-spinning of an intrinsically flame-retardant polyacrylonitrile copolymer(2020) König, Simon; Kreis, Philipp; Herbert, Christian; Wego, Andreas; Steinmann, Mark; Wang, Dongren; Frank, Erik; Buchmeiser, Michael R.Poly(acrylonitrile) (PAN) fibers have two essential drawbacks: they are usually processed by solution-spinning, which is inferior to melt spinning in terms of productivity and costs, and they are flammable in air. Here, we report on the synthesis and melt-spinning of an intrinsically flame-retardant PAN-copolymer with phosphorus-containing dimethylphosphonomethyl acrylate (DPA) as primary comonomer. Furthermore, the copolymerization parameters of the aqueous suspension polymerization of acrylonitrile (AN) and DPA were determined applying both the Fineman and Ross and Kelen and Tüdõs methods. For flame retardancy and melt-spinning tests, multiple PAN copolymers with different amounts of DPA and, in some cases, methyl acrylate (MA) have been synthesized. One of the synthesized PAN-copolymers has been melt-spun with propylene carbonate (PC) as plasticizer; the resulting PAN-fibers had a tenacity of 195 ± 40 MPa and a Young’s modulus of 5.2 ± 0.7 GPa. The flame-retardant properties have been determined by Limiting Oxygen Index (LOI) flame tests. The LOI value of the melt-spinnable PAN was 25.1; it therefore meets the flame retardancy criteria for many applications. In short, the reported method shows that the disadvantage of high comonomer content necessary for flame retardation can be turned into an advantage by enabling melt spinning.Item Open Access Integrating electronics to textiles by ultrasonic welding for cable-driven applications for smart textiles(2021) Micus, Sebastian; Rostami, Sahar Golmohammadi; Haupt, Michael; Gresser, Götz T.; Meghrazi, Milad Alizadeh; Eskandarian, LadanThe connection between flexible textiles and stiff electronic components has always been structurally weak and a limiting factor in the establishment of smart textiles in our everyday life. This paper focuses on the formation of reliable connections between conductive textiles and conventional litz wires using ultrasonic welding. The paper offers a promising approach to solving this problem. The electrical and mechanical performance of the samples were investigated after 15 and 30 wash-and-dry cycles in a laundry machine. Here the contact resistances and their peeling strength were measured. Furthermore, their connection properties were analysed in microsections. The resistance of the joints increased more than 300%, because the silver-coated wires suffered under the laundry cycles. Meanwhile, the mechanical strength during the peeling test decreased by only about 20% after 15 cycles and remained the same after 30 cycles. The good results obtained in this study suggest that ultrasonic welding offers a useful approach to the connection of textile electronics to conductive wires and to the manufacture of smart textiles.Item Open Access Method of manufacturing structural, optically transparent glass fiber-reinforced polymers (tGFRP) using infusion techniques with epoxy resin systems and E-glass fabrics(2023) Heudorfer, Klaus; Bauer, Johannes; Caydamli, Yavuz; Gompf, Bruno; Take, Jens; Buchmeiser, Michael R.; Middendorf, PeterRecently, fiber-reinforced, epoxy-based, optically transparent composites were successfully produced using resin transfer molding (RTM) techniques. Generally, the production of structural, optically transparent composites is challenging since it requires the combination of a very smooth mold surface with a sufficient control of resin flow that leads to no visible voids. Furthermore, it requires a minimum deviation of the refractive indices (RIs) of the matrix polymer and the reinforcement fibers. Here, a new mold design is described and three plates of optically transparent glass fiber-reinforced polymers (tGFRP) with reproducible properties as well as high fiber volume fractions were produced using the RTM process and in situ polymerization of an epoxy resin system enclosing E-glass fiber textiles. Their mechanical (flexural), microstructural (fiber volume fraction, surface roughness, etc.), thermal (DSC, TGA, etc.), and optical (dispersion curves of glass fibers and polymer as well as transmission over visible spectra curves of the tGFRP at varying tempering states) properties were evaluated. The research showed improved surface quality and good transmission data for samples manufactured by a new Optical-RTM setup compared to a standard RTM mold. The maximum transmission was reported to be ≈74%. In addition, no detectable voids were found in these samples. Furthermore, a flexural modulus of 23.49 ± 0.64 GPa was achieved for the Optical-RTM samples having a fiber volume fraction of ≈42%.