Universität Stuttgart
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Item Open Access Excited electronic states of flavin-containing coenzyme models(1988) Gückel, Friedemann; Schweitzer, Dieter; Becker, Katja; Schirmer, Rolf Heiner; Zipplies, Matthias F.; Staab, Heinz A.In order to gain further insight into the physical basis of flavin-catalyzed reactions, the interactions of a flavin with a second flavin and with other aromatic ring systems were studied. For this purpose compounds through 1 were synthesized These compounds contain the interacting units in defined geometric orientation. A monomeric flavin and glutathione reductase a flavoenzyme of known active-site chemistry, were included as reference molecules. The present report deals with excited triplet states of the flavin compounds as studied by optical spectroscopy and optically detected magnetic resonances (ODMR) at 1.3K.Item Open Access Self-consistent modelling of pulsar magnetospheres(1989) Herold, Heinz; Ertl, Thomas; Finkbeiner, Bernd; Ruder, HannsThe magnetosphere of a rapidly rotating, strongly magnetized neutron star with aligned magnetic and rotational axes (parallel rotator) is modelled numerically. Including the radiation of the particles accelerated to relativistic energies as an efficient damping mechanism, we obtain a quasi-stationary selfconsistent solution to this classical problem. The numerical simulation, which was started from the well-known vacuum solution, yields a global magnetospheric structure that can be characterized by two regions of oppositely charged particles, which eventually produce a relativistic pulsar wind, separated by a vacuum gap of considerable extent.Item Open Access Metallic coordination polymers using CS2 as starting material(1987) Keller, Heimo J.; Klutz, Thomas; Münstedt, Helmut; Renner, Gerd; Schweitzer, DieterOrganic polymers with "metallic" properties have found widespread interest during the last few years. Acetylene and aniline as well as different nitrogen and sulfur heterocycles have been used as starting materials. One main problem hampering the technical application of these solids up to now is their environmental and thermal instability. Therefore, we introduced metal ions to stabilize polymeric backbones with high electrical conductivity. Because of the enormous coordination ability of sulfur to many transition metal ions we decided to use a polymeric carbon-sulfur backbone.Item Open Access Organic metals from chiral BEDT-TTF donors(1991) Chen, Ben-ming; Deilacher, Frank; Hoch, Matthias; Keller, Heimo J.; Wu, Pei-ji; Gärtner, Stephan; Kahlich, Siegfried; Schweitzer, DieterWe have shown that is is possible to obtain organic metals from chiral molecules. The X-ray results prove an oxidation number of + 1.5 for the radical cations in at least two cases. To our best knowledge. these are: the first examples of BEDT-TTF-related radical cation salts with this oxidation number. As expected, we obtained statistically disordered crystals, containing the two different enantiomers in a "racemic" mixture. The broad smeared-out phase transitions are probably due to this disorder, or may be caused by the three-dimensional interactions which have been observed, so far, only once in a BEDT-TTF radical salt. We will crystallize the metallic compounds using "optically pure" isomers, in the hope to be able to isolate chiral metals.Item Open Access Simulation mit Supercomputern : ein neues Werkzeug der Physik(1990) Ruder, Hanns; Ertl, Thomas; Geyer, Florian; Herold, Heinz; Kraus, Ute; Nollert, Hans-Peter; Rebetzky, Andreas; Schweizer, Wolfgang; Zahn, CorvinUnser Wissen über die Struktur des Kosmos und die darin enthaltenen Objekte stammt aus der sorgfältigen Analyse der auf der Erde einfallenden elektromagnetischen Strahlung,verbunden mit einer theoretischen Modellierung im Rahmen der von uns erforschten Naturgesetze. Die sprunghafte Zunahme unserer Kenntnisse in den letzten zwei Jahrzehnten verdanken wir vor allem den vielen Forschungssatelliten, die die Beobachtung kosmischer Objekte ohne die störenden Einflüsse unserer Atmosphäre erlauben. Speziell im weichen Röntgenbereich ist dadurch eine Beobachtung überhaupt erst möglich , und es ist gerade dieser Spektralbereich, der uns wesentlich neue Erkenntnisse über hochinteressante Objekte geliefert hat, da intensive Röntgenstrahlung nur unter sehr extremen physikalischen Bedingungen entsteht. Die in diesen Röntgenemissionsgebieten vorherrschenden Temperaturen, Magnet- und Gravitationsfelder sind so extrem, daß sie in irdischen Labors nicht realisiert werden können. Folglich bleibt nur die Möglichkeit, die Eigenschaften der Materie und die unter diesen Bedingungen ablaufenden physikalischen Prozesse theoretisch zu berechnen, um so - im Vergleich mit den Beobachtungen - zu zuverlässigen Aussagen über die Struktur dieser kosmischen Objekte zu gelangen.Item Open Access ODMR of triplet states of organic electron donors(1986) Grimm, Hans; Schweitzer, Dieter; Hausser, Karl H.; Keller, Heimo J.Energies of the first excited triplet states and triplet zero field splitting parameters /D/ and /E/ of several organic donors - usually used for the preparation of organic metals and superconductors - are reported.Item Open Access Influence of defects on the splitting of the acceptor ground state in silicon(1984) Ambrosy, Anton; Lassmann, Kurt; Goer, Anne M. de; Salce, Bernard; Zeile, Heinrich-Item Open Access BEDT-TTF radical salts: organic metals and superconductors(1987) Schweitzer, DieterA review of the structural, electronic and superconducting properties of some BEDT-TTF-radical salts is given.Item Open Access Proton relaxation in the superconducting organic solid (BEDT-TTF)2Cu(NCS)2: evidence for relaxation by localized paramagnetic centers(1990) Klutz, Thomas; Haeberlen, Ulrich; Schweitzer, DieterThe nonexponential character of the build-up of the nuclear magnetization usually increases on lowering the temperature. Superconducting fluctuations have been offered in a speculative way as an explanation for the nonexponential spin relaxation. We have observed the same relaxation behaviour in our investigation of the proton spin relaxation in (BEDT-TTF)2Cu(NCS)2 which is an organic conductor at room temperature and becomes a superconductor at Tc=10.4 K at ambient pressure. As we noticed during preliminary measurements that the degree of deviation from exponential relaxation depends on the sample under study we decided to do experiments under controlled conditions of sample preparation.Item Open Access Kinematics and dynamics for computer animation(1994) Ruder, Hanns; Ertl, Thomas; Gruber, Karin; Günther, Michael; Hospach, Frank; Ruder, Margret; Subke, Jörg; Widmayer, KarinThis tutorial will focus on the physical principles of kinematics and dynamics. After explaining the basic equations for point masses and rigid bodies a new approach for the dynamic simulation of multi-linked models with wobbling mass is presented, which has led to new insight in the field of biomechanics, but which has not been used in computer animation so far.