Universität Stuttgart
Permanent URI for this communityhttps://elib.uni-stuttgart.de/handle/11682/1
Browse
17 results
Search Results
Item Open Access Organic metals from chiral BEDT-TTF donors(1991) Chen, Ben-ming; Deilacher, Frank; Hoch, Matthias; Keller, Heimo J.; Wu, Pei-ji; Gärtner, Stephan; Kahlich, Siegfried; Schweitzer, DieterWe have shown that is is possible to obtain organic metals from chiral molecules. The X-ray results prove an oxidation number of + 1.5 for the radical cations in at least two cases. To our best knowledge. these are: the first examples of BEDT-TTF-related radical cation salts with this oxidation number. As expected, we obtained statistically disordered crystals, containing the two different enantiomers in a "racemic" mixture. The broad smeared-out phase transitions are probably due to this disorder, or may be caused by the three-dimensional interactions which have been observed, so far, only once in a BEDT-TTF radical salt. We will crystallize the metallic compounds using "optically pure" isomers, in the hope to be able to isolate chiral metals.Item Open Access Simulation mit Supercomputern : ein neues Werkzeug der Physik(1990) Ruder, Hanns; Ertl, Thomas; Geyer, Florian; Herold, Heinz; Kraus, Ute; Nollert, Hans-Peter; Rebetzky, Andreas; Schweizer, Wolfgang; Zahn, CorvinUnser Wissen über die Struktur des Kosmos und die darin enthaltenen Objekte stammt aus der sorgfältigen Analyse der auf der Erde einfallenden elektromagnetischen Strahlung,verbunden mit einer theoretischen Modellierung im Rahmen der von uns erforschten Naturgesetze. Die sprunghafte Zunahme unserer Kenntnisse in den letzten zwei Jahrzehnten verdanken wir vor allem den vielen Forschungssatelliten, die die Beobachtung kosmischer Objekte ohne die störenden Einflüsse unserer Atmosphäre erlauben. Speziell im weichen Röntgenbereich ist dadurch eine Beobachtung überhaupt erst möglich , und es ist gerade dieser Spektralbereich, der uns wesentlich neue Erkenntnisse über hochinteressante Objekte geliefert hat, da intensive Röntgenstrahlung nur unter sehr extremen physikalischen Bedingungen entsteht. Die in diesen Röntgenemissionsgebieten vorherrschenden Temperaturen, Magnet- und Gravitationsfelder sind so extrem, daß sie in irdischen Labors nicht realisiert werden können. Folglich bleibt nur die Möglichkeit, die Eigenschaften der Materie und die unter diesen Bedingungen ablaufenden physikalischen Prozesse theoretisch zu berechnen, um so - im Vergleich mit den Beobachtungen - zu zuverlässigen Aussagen über die Struktur dieser kosmischen Objekte zu gelangen.Item Open Access Proton relaxation in the superconducting organic solid (BEDT-TTF)2Cu(NCS)2: evidence for relaxation by localized paramagnetic centers(1990) Klutz, Thomas; Haeberlen, Ulrich; Schweitzer, DieterThe nonexponential character of the build-up of the nuclear magnetization usually increases on lowering the temperature. Superconducting fluctuations have been offered in a speculative way as an explanation for the nonexponential spin relaxation. We have observed the same relaxation behaviour in our investigation of the proton spin relaxation in (BEDT-TTF)2Cu(NCS)2 which is an organic conductor at room temperature and becomes a superconductor at Tc=10.4 K at ambient pressure. As we noticed during preliminary measurements that the degree of deviation from exponential relaxation depends on the sample under study we decided to do experiments under controlled conditions of sample preparation.Item Open Access The morphology of ice structure in a parallel plate channel(1991) Weigand, Bernhard; Beer, HansAn experimental study has been performed to investigate the ice formation phenomena of water flow between two horizontal cooled parallel plates. A detailed and comprehensive investigation of the morphology of the ice-structure is given. It is shown that the different shapes of ice-layers can be classified with the help of a Θc - ReD diagramm. The regions for which a certain type of ice-layer occures are clearly separated.Item Open Access Bulk superconductivity at ambient pressure in polycrystalline pressed samples of organic metals(1990) Schweitzer, Dieter; Kahlich, Siegfried; Gärtner, Stephan; Gogu, Emil; Grimm, Hans; Zamboni, Roberto; Keller, Heimo J.Bulk superconductivity in polycrystalline pressed samples of αt-(BEDT-TTF)2I3 and βp-(BEDT-TTF)2I3 is reported. This finding shows that organic superconductors can be used in principle for the preparation of electronic devices and superconducting cables.Item Open Access Self-consistent numerical modelling of pulsar magnetospheres(1992) Herold, Heinz; Ertl, Thomas; Finkbeiner, Bernd; Ruder, HannsThe magnetosphere of a rapidly rotating, strongly magnetized neutron star with aligned magnetic and rotational axes (parallel rotator) is modelled numerically. Including the radiation of the particles accelerated to relativistic energies as an efficient damping mechanism, we obtain a quasi-stationary self-consistent solution to this classical problem. The numerical simulation,which was started from the well-known vacuum solution, yields a global magnetospheric structure that can be characterized by two regions of oppositely charged particles, which eventually produce a relativistic pulsar wind, separated by a vacuum gap of considerable extent.Item Open Access Electric-field profiles in corona- or electron-beam-charged and thermally treated Teflon PTFE, FEP, and PFA films(1992) Gerhard-Multhaupt, Reimund; Eberle, Gernot; Xia, Zhongfou; Yang, Guomao; Eisenmenger, WolfgangCharge spreading in three different types of Teflon electrets was studied by means of piezoelectrically generated pressure steps, FEP and PFA samples corona-charged at room temperature usually exhibited only a surface charge layer. Uniform charge spreading throughout the bulk was found in FEP charged at or heated to high temperatures. Charge spreading was much less prominent in PFA because of a smaller retrapping efficiency. In PTFE (polytetrafluorethylene), charges from the surface and the rear electrode were injected into the bulk during charging at any temperature. Electron-beam-deposited charge layers broadened significantly upon heating.Item Open Access Fluid flow and heat transfer in an axially rotating pipe: the rotational entrance(1992) Weigand, Bernhard; Beer, HansThe complex interactions between turbulence and rotation in the rotational entrance region of a pipe, rotating about its axis, are examined. By assuming, a universal tangential velocity profile and with the use of a modified mixing length theory, the development of the axial velocIty profile and the heat transfer coefficient along the rotational entrance length are calculated. The theoretical results are compared with experimental flndings of Reich.Item Open Access Transport properties of single crystals and polycristalline pressed samples of (BEDT-TTF)2X salts and related coordination polymers(1991) Schweitzer, Dieter; Kahlich, Siegfried; Gärtner, Stephan; Gogu, Emil; Grimm, Hans; Heinen, Ilsabe; Klutz, Thomas; Zamboni, Roberto; Keller, Heimo J.; Renner, GerdTen years ago in 1979, superconductivity was observed for the first time in an organic metal. today, about 30 different organic metals are known, which become superconducting under pressure or ambient pressure. The organic superconductors with the highest transition temperatures are all radical salts of the donor bis(ethylenedithioio)-tettathiafulvalene (BEDT-TTF), namely at ambient pressure (BEDT-TTF)2CU(NCS)2 (Tc = 10.4 K) and αt,-(BEDT-TTF)2I3 (Tc = 8 K) and under isotropic pressure β H- (BEDT-TTF)2I3(0.5 kbar, Tc = 7.5 K) The latter β H-phase can even become superconducting at 8 K and ambient pressure, after a special pressure-temperature cycling procedure i.e. pressurization up to 1 kbar at room temperature, and release of the helium gas pressure at temperarures below 125 K. Nevertheless, this superconducting state at 8 K in β H-(BEDT -TTF)2I3 is only metastable , since warming up the crystal above 125 K and cooling down again under ambient pressure, results only in superconductivity at 1.3 K, the so-called β L - or β-phase.Item Open Access Computersimulation in der Astrophysik(1990) Ruder, Hanns; Ertl, Thomas; Geyer, Florian; Herold, Heinz; Kraus, Ute; Nollert, Hans-Peter; Rebetzky, Andreas; Zahn, CorvinUnser Wissen über die Struktur des Kosmos und die darin enthaltenen Objekte stammt aus der sorgfältigen Analyse der einfallenden elektromagnetischen Strahlung, verbunden mit einer theoretischen Modellierung im Rahmen der von uns erforschten Naturgesetze. Die Beobachtungen erstrecken sich dabei heute vom Radiowellenbereich über den Infrarot-, den optischen, den Röntgenbereich bis hin zum Höchstenergie-Gamma-Bereich, also über mehr als 20 Dekaden des elektromagnetischen Spektrums. Eine realistische Modellierung der Systeme im Rahmen einer beobachtungsnahen Theorie erfordert vor allem bei Systemparameterstudien im allgemeinen den Einsatz der größten verfügbaren Rechenleistungen.