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Publication Type: search.filters.UBSTyp.KonferenzbeitragSubject: search.filters.subject.530Start date: 1990End date: 1991

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Now showing 1 - 10 of 24
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    Dynamics of poling PVDF between 25°C and 120°C
    (1991) Eberle, Gernot; Eisenmenger, Wolfgang
    PVDF films with high β-content are poled in an electric field of 60 MV/m at temperatures between 25°C and 120°C. At 25°C the alignment of dipoles takes place in a central poling zone during several hours of poling. When the temperature is increased to 120°C the poling time necessary to align the dipoles in this narrow zone is reduced to several seconds. In addition, at temperatures higher than 90°C and increased poling times the central poling zone first increases but later decreases in its dielectric displacement. Simultaneously in a 10 μm regime adjoining the positive electrode a secondary displacement zone starts to grow. The strong reduction of this peak under short circuit conditions indicates hetero-charge accumulation in front of an anode.
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    Organic metals from chiral BEDT-TTF donors
    (1991) Chen, Ben-ming; Deilacher, Frank; Hoch, Matthias; Keller, Heimo J.; Wu, Pei-ji; Gärtner, Stephan; Kahlich, Siegfried; Schweitzer, Dieter
    We have shown that is is possible to obtain organic metals from chiral molecules. The X-ray results prove an oxidation number of + 1.5 for the radical cations in at least two cases. To our best knowledge. these are: the first examples of BEDT-TTF-related radical cation salts with this oxidation number. As expected, we obtained statistically disordered crystals, containing the two different enantiomers in a "racemic" mixture. The broad smeared-out phase transitions are probably due to this disorder, or may be caused by the three-dimensional interactions which have been observed, so far, only once in a BEDT-TTF radical salt. We will crystallize the metallic compounds using "optically pure" isomers, in the hope to be able to isolate chiral metals.
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    Simulation mit Supercomputern : ein neues Werkzeug der Physik
    (1990) Ruder, Hanns; Ertl, Thomas; Geyer, Florian; Herold, Heinz; Kraus, Ute; Nollert, Hans-Peter; Rebetzky, Andreas; Schweizer, Wolfgang; Zahn, Corvin
    Unser Wissen über die Struktur des Kosmos und die darin enthaltenen Objekte stammt aus der sorgfältigen Analyse der auf der Erde einfallenden elektromagnetischen Strahlung,verbunden mit einer theoretischen Modellierung im Rahmen der von uns erforschten Naturgesetze. Die sprunghafte Zunahme unserer Kenntnisse in den letzten zwei Jahrzehnten verdanken wir vor allem den vielen Forschungssatelliten, die die Beobachtung kosmischer Objekte ohne die störenden Einflüsse unserer Atmosphäre erlauben. Speziell im weichen Röntgenbereich ist dadurch eine Beobachtung überhaupt erst möglich , und es ist gerade dieser Spektralbereich, der uns wesentlich neue Erkenntnisse über hochinteressante Objekte geliefert hat, da intensive Röntgenstrahlung nur unter sehr extremen physikalischen Bedingungen entsteht. Die in diesen Röntgenemissionsgebieten vorherrschenden Temperaturen, Magnet- und Gravitationsfelder sind so extrem, daß sie in irdischen Labors nicht realisiert werden können. Folglich bleibt nur die Möglichkeit, die Eigenschaften der Materie und die unter diesen Bedingungen ablaufenden physikalischen Prozesse theoretisch zu berechnen, um so - im Vergleich mit den Beobachtungen - zu zuverlässigen Aussagen über die Struktur dieser kosmischen Objekte zu gelangen.
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    High frequency phonon transmission through amorphous films
    (1990) Mebert, Joachim; Maile, Bernd; Eisenmenger, Wolfgang
    We now report on phonon spectroscopy measurements in the frequency range from 300 GHz - 1 THz on thin amorphous films of several materials (i.e. e-beam evaporated SiO2., α-Si and α-Ge). Some films were prepared in a residual gas atmosphere as H20 and N2.
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    Polarization distribution in PVDF obtained by poling under constant current condition
    (1990) Neumann, Guido; Bihler, Eckardt; Eberle, Gernot; Eisenmenger, Wolfgang
    Since the resistivity of PVDE films increases when the films are poled, the voltage across the samples must be increased during the poling process in order to keep the current constant. Under these conditions, the formation of a polarization zone in the center of the film depth is observed. The thickness of the polarization-free zone close to the film surfaces is found to decrease with larger current densities. The results are consistent with a model assuming charge trapping in deep traps associated with the orientation of polar crystallites.
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    Phono-conduction spectroscopy of shallow states in semiconductors
    (1990) Lassmann, Kurt; Gienger, Martin; Groß, Peter
    Phonoconduction spectroscopy of shallow states in semiconductors by help of superconduction Al-junctions as phonon sources with high spectral resolution is a sensitive new technique with phonon frequencies well up in the Debye range. The large k-vector of the phonons involved opens new possibilities for the investigation of electron dynamics and states in semiconductors.
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    Proton relaxation in the superconducting organic solid (BEDT-TTF)2Cu(NCS)2: evidence for relaxation by localized paramagnetic centers
    (1990) Klutz, Thomas; Haeberlen, Ulrich; Schweitzer, Dieter
    The nonexponential character of the build-up of the nuclear magnetization usually increases on lowering the temperature. Superconducting fluctuations have been offered in a speculative way as an explanation for the nonexponential spin relaxation. We have observed the same relaxation behaviour in our investigation of the proton spin relaxation in (BEDT-TTF)2Cu(NCS)2 which is an organic conductor at room temperature and becomes a superconductor at Tc=10.4 K at ambient pressure. As we noticed during preliminary measurements that the degree of deviation from exponential relaxation depends on the sample under study we decided to do experiments under controlled conditions of sample preparation.
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    Dual wavelength heterodyne interferometry for rough surface measurements
    (1990) Fischer, Edgar; Sodnik, Zoran; Ittner, Thomas; Tiziani, Hans J.
    For interferometric topography measurements of optically rough surfaces dual wavelength heterodyne Interferometry (DWHI) is a powerful tool. A DWHI system based on a two-wavelength HeNe laser and a matched grating technique is described. This set-up improves system stability and simple heterodyne frequency generation.
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    The morphology of ice structure in a parallel plate channel
    (1991) Weigand, Bernhard; Beer, Hans
    An experimental study has been performed to investigate the ice formation phenomena of water flow between two horizontal cooled parallel plates. A detailed and comprehensive investigation of the morphology of the ice-structure is given. It is shown that the different shapes of ice-layers can be classified with the help of a Θc - ReD diagramm. The regions for which a certain type of ice-layer occures are clearly separated.
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    Bulk superconductivity at ambient pressure in polycrystalline pressed samples of organic metals
    (1990) Schweitzer, Dieter; Kahlich, Siegfried; Gärtner, Stephan; Gogu, Emil; Grimm, Hans; Zamboni, Roberto; Keller, Heimo J.
    Bulk superconductivity in polycrystalline pressed samples of αt-(BEDT-TTF)2I3 and βp-(BEDT-TTF)2I3 is reported. This finding shows that organic superconductors can be used in principle for the preparation of electronic devices and superconducting cables.