Universität Stuttgart
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Item Open Access Analytic free-energy expression for the 2D-Ising model and perspectives for battery modeling(2023) Markthaler, Daniel; Birke, Kai PeterAlthough originally developed to describe the magnetic behavior of matter, the Ising model represents one of the most widely used physical models, with applications in almost all scientific areas. Even after 100 years, the model still poses challenges and is the subject of active research. In this work, we address the question of whether it is possible to describe the free energy A of a finite-size 2D-Ising model of arbitrary size, based on a couple of analytically solvable 1D-Ising chains. The presented novel approach is based on rigorous statistical-thermodynamic principles and involves modeling the free energy contribution of an added inter-chain bond DAbond(b, N) as function of inverse temperature b and lattice size N. The identified simple analytic expression for DAbond is fitted to exact results of a series of finite-size quadratic N N-systems and enables straightforward and instantaneous calculation of thermodynamic quantities of interest, such as free energy and heat capacity for systems of an arbitrary size. This approach is not only interesting from a fundamental perspective with respect to the possible transfer to a 3D-Ising model, but also from an application-driven viewpoint in the context of (Li-ion) batteries where it could be applied to describe intercalation mechanisms.Item Open Access Anti-adhesive surfaces inspired by bee mandible surfaces(2023) Saccardi, Leonie; Schiebl, Jonas; Balluff, Franz; Christ, Ulrich; Gorb, Stanislav N.; Kovalev, Alexander; Schwarz, OliverPropolis, a naturally sticky substance used by bees to secure their hives and protect the colony from pathogens, presents a fascinating challenge. Despite its adhesive nature, honeybees adeptly handle propolis with their mandibles. Previous research has shown a combination of an anti-adhesive fluid layer and scale-like microstructures on the inner surface of bee mandibles. Our aim was to deepen our understanding of how surface energy and microstructure influence the reduction in adhesion for challenging substances like propolis. To achieve this, we devised surfaces inspired by the intricate microstructure of bee mandibles, employing diverse techniques including roughening steel surfaces, creating lacquer structures using Bénard cells, and moulding resin surfaces with hexagonal patterns. These approaches generated patterns that mimicked the bee mandible structure to varying degrees. Subsequently, we assessed the adhesion of propolis on these bioinspired structured substrates. Our findings revealed that on rough steel and resin surfaces structured with hexagonal dimples, propolis adhesion was significantly reduced by over 40% compared to unstructured control surfaces. However, in the case of the lacquer surface patterned with Bénard cells, we did not observe a significant reduction in adhesion.Item Open Access A performance and cost overview of selected solid-state electrolytes : race between polymer electrolytes and inorganic sulfide electrolytes(2021) Karabelli, Duygu; Birke, Kai Peter; Weeber, MaxElectrolytes are key components in electrochemical storage systems, which provide an ion-transport mechanism between the cathode and anode of a cell. As battery technologies are in continuous development, there has been growing demand for more efficient, reliable and environmentally friendly materials. Solid-state lithium ion batteries (SSLIBs) are considered as next-generation energy storage systems and solid electrolytes (SEs) are the key components for these systems. Compared to liquid electrolytes, SEs are thermally stable (safer), less toxic and provide a more compact (lighter) battery design. However, the main issue is the ionic conductivity, especially at low temperatures. So far, there are two popular types of SEs: (1) inorganic solid electrolytes (InSEs) and (2) polymer electrolytes (PEs). Among InSEs, sulfide-based SEs are providing very high ionic conductivities (up to 10−2 S/cm) and they can easily compete with liquid electrolytes (LEs). On the other hand, they are much more expensive than LEs. PEs can be produced at less cost than InSEs but their conductivities are still not sufficient for higher performances. This paper reviews the most efficient SEs and compares them in terms of their performances and costs. The challenges associated with the current state-of-the-art electrolytes and their cost-reduction potentials are described.Item Open Access Influence of exoskeleton use on Cardiac Index(2022) Schalk, Marco; Schalk, Ines; Bauernhansl, Thomas; Siegert, Jörg; Schneider, UrsThis study aims to assess the whole-body physiological effects of wearing an exoskeleton during a one-hour standardized work task, utilizing the Cardiac Index (CI) as the target parameter. N = 42 young and healthy subjects with welding experience took part in the study. The standardized and abstracted one-hour workflow consists of simulated welding and grinding in constrained body positions and was completed twice by each subject, with and without an exoskeleton, in a randomized order. The CI was measured by Impedance Cardiography (ICG), an approved medical method. The difference between the averaged baseline measurement and the averaged last 10 min was computed for the conditions with and without an exoskeleton for each subject to result in ∆CIwithout exo and ∆CIwith exo. A significant difference between the conditions with and without an exoskeleton was found, with the reduction in CI when wearing an exoskeleton amounting to 10.51%. This result corresponds to that of previous studies that analyzed whole-body physiological load by means of spiroergometry. These results suggest a strong positive influence of exoskeletons on CI and, therefore, physiological load. At the same time, they also support the hypothesis that ICG is a suitable measurement instrument to assess these effects.Item Open Access Process model and life cycle assessment of biorefinery concept using agricultural and industrial residues for biohydrogen production(2024) Gamero, Edgar; Ruppert, Sophia; Miehe, Robert; Sauer, AlexanderSustainable waste management strategies are urgently needed due to an increasing global population and increased waste production. In this context, biorefineries have recently emerged as a promising approach to valorize waste streams and supply a broad range of products. This study presents the process model and life cycle assessment (LCA) of a biorefinery concept using a novel biochemical method, a so-called “dark photosynthesis” conversion. This process is coupled to a photo-fermentation using microalgae. Overall, the biorefinery concept can produce hydrogen, lutein, β-carotene, and proteins for animal feed. Apple pomace from apple juice production is used as feedstock for the primary conversion step. A process model was created with the process simulation software Aspen Plus ® using experimental and literature data. Results from this model were then used in an LCA. The environmental impacts of the proposed biorefinery concept are relatively high, showing the need for process optimization in several areas. Energy system integration, stream recycling, and higher hydrogen yields are recognized as especially important for improving the environmental performance of this concept. Despite these findings, the model shows the feasibility of implementing the biochemical conversion technologies in a biorefinery concept for effectively utilizing residue streams.Item Open Access An exploratory analysis of the current status and potential of service-oriented and data-driven business models within the sheet metal working sector : insights from interview-based research in small and medium-sized enterprises(2024) Wirth, Jonas; Schneider, Mirko; Hanselmann, Leon; Fink, Kira; Nebauer, Stephan; Bauernhansl, ThomasResponding to changing value creation processes in the sheet metal working sector, where the complexity and interchangeability of products challenge traditional differentiation strategies, this exploratory analysis examines the integration of service-oriented and data-driven business models as new paths to ensure competitiveness, especially for small and medium-sized enterprises (SMEs). This study aims to capture the current state and challenges associated with the implementation of these business models in this sector. This research was conducted through semi-structured interviews with SMEs in the industry. The findings indicate that service-oriented and data-driven business models are not yet widely adopted and that manufacturing companies require support in their implementation. Fields of action were identified for the industry. These are “Creating awareness and understanding”, “Recognizing added value”, “Increasing company maturity”, and “Understanding the change process”. Cooperation between science and industry is essential in tackling these fields of action to ensure the successful integration of such business models in manufacturing companies. This paper identifies challenges in the fields of action that companies must address through a structured approach, promoting awareness, recognizing value, improving organizational maturity, and understanding the change process to successfully implement service-oriented and data-driven business models.Item Open Access A methodology to systematically identify and characterize energy flexibility measures in industrial systems(2020) Tristán, Alejandro; Heuberger, Flurina; Sauer, AlexanderIndustrial energy flexibility enables companies to optimize their energy-associated production costs and support the energy transition towards renewable energy sources. The first step towards achieving energy flexible operation in a production facility is to identify and characterize the energy flexibility measures available in the industrial systems that comprise it. These industrial systems are both the manufacturing systems that directly execute the production tasks and the systems performing supporting tasks or tasks necessary for the operation of these manufacturing systems. Energy flexibility measures are conscious and quantifiable actions to carry out a defined change of operative state in an industrial system. This work proposes a methodology to identify and characterize the available energy flexibility measures in industrial systems regardless of the task they perform in the facility. This methodology is the basis of energy flexibility-oriented industrial energy audits, in juxtaposition with the current industrial energy audits that focus on energy efficiency. This audit will provide industrial enterprises with a qualitative and quantitative understanding of the capabilities of their industrial systems, and hence their production facilities, for energy flexible operation. The audit results facilitate a company’s decision making towards the implementation, evaluation and management of these capabilities.Item Open Access Enzyme-assisted circular additive manufacturing as an enabling technology for a circular bioeconomy : a conceptual review(2024) Protte-Freitag, Kristin; Gotzig, Sophia; Rothe, Hannah; Schwarz, Oliver; Silber, Nadine; Miehe, RobertAdditive manufacturing (AM) is a decisive element in the sustainable transformation of technologies. And yet its inherent potential has not been fully utilized. In particular, the use of biological materials represents a comparatively new dimension that is still in the early stages of deployment. In order to be considered sustainable and contribute to the circular economy, various challenges need to be overcome. Here, the literature focusing on sustainable, circular approaches is reviewed. It appears that existing processes are not yet capable of being used as circular economy technologies as they are neither able to process residual and waste materials, nor are the produced products easily biodegradable. Enzymatic approaches, however, appear promising. Based on this, a novel concept called enzyme-assisted circular additive manufacturing was developed. Various process combinations using enzymes along the process chain, starting with the preparation of side streams, through the functionalization of biopolymers to the actual printing process and post-processing, are outlined. Future aspects are discussed, stressing the necessity for AM processes to minimize or avoid the use of chemicals such as solvents or binding agents, the need to save energy through lower process temperatures and thereby reduce CO2 consumption, and the necessity for complete biodegradability of the materials used.Item Open Access Simulation modeling for energy-flexible manufacturing : pitfalls and how to avoid them(2022) Köberlein, Jana; Bank, Lukas; Roth, Stefan; Köse, Ekrem; Kuhlmann, Timm; Prell, Bastian; Stange, Maximilian; Münnich, Marc; Flum, Dominik; Moog, Daniel; Ihlenfeldt, Steffen; Sauer, Alexander; Weigold, Matthias; Schilp, JohannesDue to the high share of industry in total electricity consumption, industrial demand-side management can make a relevant contribution to the stability of power systems. At the same time, companies get the opportunity to reduce their electricity procurement costs by taking advantage of increasingly fluctuating prices on short-term electricity markets, the provision of system services on balancing power markets, or by increasing the share of their own consumption from on-site generated renewable energy. Demand-side management requires the ability to react flexibly to the power supply situation without negatively affecting production targets. It also means that the management and operation of production must consider not only production-related parameters but also parameters of energy availability, which further increase the complexity of decision-making. Although simulation studies are a recognized tool for supporting decision-making processes in production and logistics, the simultaneous simulation of material and energy flows has so far been limited mainly to issues of energy efficiency as opposed to energy flexibility, where application-oriented experience is still limited. We assume that the consideration of energy flexibility in the simulation of manufacturing systems will amplify already known pitfalls in conducting simulation studies. Based on five representative industrial use cases, this article provides practitioners with application-oriented experiences of the coupling of energy and material flows in simulation modeling of energy-flexible manufacturing, identifies challenges in the simulation of energy-flexible production systems, and proposes approaches to face these challenges. Seven pitfalls that pose a particular challenge in simulating energy-flexible manufacturing have been identified, and possible solutions and measures for avoiding them are shown. It has been found that, among other things, consistent management of all parties involved, early clarification of energy-related, logistical, and resulting technical requirements for models and software, as well as the application of suitable methods for validation and verification are central to avoiding these pitfalls. The identification and characterization of challenges and the derivation of recommendations for coping with them can raise awareness of typical pitfalls. This paper thus helps to ensure that simulation studies of energy-flexible production systems can be carried out more efficiently in the future.Item Open Access Comparison of the temperature, radiation, and heat flux distribution of a hydrogen and a methane flame in a crucible furnace using numerical simulation(2024) Mages, Alexander; Sauer, AlexanderSustainable technologies to replace current fossil solutions are essential to meet future CO2 emission reduction targets. Therefore, this paper compares key performance indicators of a hydrogen- and a methane-flame-fired crucible furnace with computational fluid dynamics simulations at identical firing powers, aiming to fully decarbonize the process. Validated numerical models from the literature were used to compare temperatures, radiation fields, radiation parameters and heat transfer characteristics. As a result, we observed higher combustion temperatures and a 19.0% higher fuel utilization rate in the hydrogen case, indicating more efficient operating modes, which could be related to the increased radiant heat flux and temperature ranges above 1750 K. Furthermore, higher scattering of the heat flux distribution on the crucible surface could be determined indicating more uneven melt bath temperatures. Further research could focus on quantifying the total fuel consumption required for the heating up of the furnace, for which a transient numerical model could be developed.