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    Werner Eissner (1930-2022) : a pioneer in computational atomic physics
    (2023) Bhatia, Anand K.; Lynas-Gray, Anthony E.; Mendoza, Claudio; Nahar, Sultana; Nussbaumer, Harry; Pradhan, Anil K.; Seaton, Anthony M.; Wunner, Günter; Zeippen, Claude J.
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    Analysis of the fine structure of the D‐exciton shell in cuprous oxide
    (2021) Heckötter, Julian; Rommel, Patric; Main, Jörg; Aßmann, Marc; Bayer, Manfred
    The exciton states in cuprous oxide show a pronounced fine structure splitting associated with the crystal environment and the resulting electronic band structure. High‐resolution spectroscopy reveals an especially pronounced splitting of the yellow D excitons with one state pushed above any other state with the same principal quantum number. This large splitting offset is related to a strong mixing of these D states with the 1S exciton of the green series, as suggested by previously published calculations. Here, a detailed comparison of this theory with experimental data is given, which leads to a complete reassignment of the experimentally observed D exciton lines. The origin of different amounts of green admixture to D‐envelope states is deduced by analyzing the different terms of the Hamiltonian. The yellow-green mixing leads to level repulsion and induces an exchange interaction splitting to D‐envelope states, from which one of them becomes the highest state within each multiplet. Furthermore, the assignment of D exciton states according to their total angular momentum F is given and corrects an earlier description given in a former study.
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    A quantum heat engine driven by atomic collisions
    (2021) Bouton, Quentin; Nettersheim, Jens; Burgardt, Sabrina; Adam, Daniel; Lutz, Eric; Widera, Artur
    Quantum heat engines are subjected to quantum fluctuations related to their discrete energy spectra. Such fluctuations question the reliable operation of thermal machines in the quantum regime. Here, we realize an endoreversible quantum Otto cycle in the large quasi-spin states of Cesium impurities immersed in an ultracold Rubidium bath. Endoreversible machines are internally reversible and irreversible losses only occur via thermal contact. We employ quantum control to regulate the direction of heat transfer that occurs via inelastic spin-exchange collisions. We further use full-counting statistics of individual atoms to monitor quantized heat exchange between engine and bath at the level of single quanta, and additionally evaluate average and variance of the power output. We optimize the performance as well as the stability of the quantum heat engine, achieving high efficiency, large power output and small power output fluctuations.
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    Quantum cooling : thermodynamics and information
    (2023) Soldati, Rodolfo R.; Lutz, Eric (Prof. Dr.)
    The theory of cooling is an important corner of thermodynamics, underlying many modern technological applications. As the field of quantum thermodynamics advances, refrigeration techniques must keep pace to fuel the innovations of quantum technologies. We study quantum cooling from its foundations to laboratory implementations within the specific paradigm of heat bath algorithmic cooling. Our study includes a detail modeling of experimental imperfections and establishes the fundamental cooling limits of the model, consolidating the algorithm as a viable quantum refrigeration method. Next, by developing the notion of virtual qubits, we demonstrate a cooling-boost protocol fueled by quantum coherences which is robust to experimental implementations. Aiming at aiding in the progress of refrigeration technologies, we conclude by studying the zero temperature equilibrium properties of a many-body system that can accommodate an autonomous quantum absorption refrigerator, and calculate its entanglement and critical properties, two features that, like quantum coherences, promise to improve the performance of quantum coolers.
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    Generalized Clausius inequalities in a nonequilibrium cold-atom system
    (2023) Mayer, Daniel; Lutz, Eric; Widera, Artur
    Thermodynamic inequalities, such as the Clausius inequality, characterize the direction of nonequilibrium processes. However, the latter result presupposes a system coupled to a heat bath that drives it to a thermal state. Far from equilibrium, the Clausius inequality can be generalized using information-theoretic quantities. For initially isolated systems that are moved from an equilibrium state by a dissipative heat exchange, the generalized Clausius inequality is predicted to be reversed. We here experimentally investigate the nonequilibrium thermodynamics of an initially isolated dilute gas of ultracold Cesium atoms that can be either thermalized or pushed out of equilibrium by means of laser cooling techniques. We determine in both cases the phase-space dynamics by tracing the evolution with position-resolved fluorescence imaging, from which we evaluate all relevant thermodynamic quantities. We confirm the validity of the generalized Clausius inequality for the first process and of the reversed generalized Clausius inequality for the second transformation.