Bitte benutzen Sie diese Kennung, um auf die Ressource zu verweisen:
http://dx.doi.org/10.18419/opus-14400
Langanzeige der Metadaten
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Schlindwein, Simon H. | - |
dc.contributor.author | Nieger, Martin | - |
dc.contributor.author | Gudat, Dietrich | - |
dc.date.accessioned | 2024-05-27T11:20:50Z | - |
dc.date.available | 2024-05-27T11:20:50Z | - |
dc.date.issued | 2021 | de |
dc.identifier.issn | 1099-0682 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.other | 1890907286 | - |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-144193 | de |
dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/14419 | - |
dc.identifier.uri | http://dx.doi.org/10.18419/opus-14400 | - |
dc.description.abstract | Reaction of a phosphane‐decorated benzenedithiol (pbdtH2) with coinage metal salts furnished polynuclear complexes [M2(pbdtH)2] (M=AuI) or [cat][M5(pbdt)3] (cat=unipositive cation, M=AgI, CuI), which were characterized by analytical and spectroscopic techniques and single‐crystal X‐ray diffraction studies. Furthermore, a double salt with an anion [Ag5(pbdt)3(PPh3)]- that proved unstable in solution was characterized crystallographically. The spectroscopic and crystallographic data revealed that the Cu(I) and Ag(I) complexes exhibit, despite their like stoichiometric composition, isomeric molecular structures. The observed disparities were reproduced by DFT studies. The dinuclear Au(I) complex was found to undergo air‐oxidation to furnish a mixed‐valent complex [(AuIII)2(AuI)2(pbdt)4]. The copper(I) - but not the isomeric silver(I) complexes - showed luminescence in the solid state. | en |
dc.description.sponsorship | The state of Baden-Württemberg through bwHPC | de |
dc.description.sponsorship | German Research Foundation (DFG) | de |
dc.description.sponsorship | Projekt DEAL | de |
dc.language.iso | en | de |
dc.relation.uri | doi:10.1002/ejic.202001026 | de |
dc.rights | info:eu-repo/semantics/openAccess | de |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | de |
dc.subject.ddc | 540 | de |
dc.title | Small variations, big impact : structural diversity of the complexes of a phosphane‐decorated benzenedithiol with group‐11 metals | en |
dc.type | article | de |
dc.date.updated | 2023-11-14T04:27:18Z | - |
ubs.fakultaet | Chemie | de |
ubs.fakultaet | Fakultätsübergreifend / Sonstige Einrichtung | de |
ubs.institut | Institut für Anorganische Chemie | de |
ubs.institut | Fakultätsübergreifend / Sonstige Einrichtung | de |
ubs.publikation.seiten | 748-755 | de |
ubs.publikation.source | European journal of inorganic chemistry 2021 (2021), S. 748-755 | de |
ubs.publikation.typ | Zeitschriftenartikel | de |
Enthalten in den Sammlungen: | 03 Fakultät Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
---|---|---|---|---|
EJIC_EJIC202001026.pdf | 2,66 MB | Adobe PDF | Öffnen/Anzeigen |
Diese Ressource wurde unter folgender Copyright-Bestimmung veröffentlicht: Lizenz von Creative Commons