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http://dx.doi.org/10.18419/opus-14412
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| DC Element | Wert | Sprache |
|---|---|---|
| dc.contributor.author | De Jesus Silva, Jordan | - |
| dc.contributor.author | Mance, Deni | - |
| dc.contributor.author | Pucino, Margherita | - |
| dc.contributor.author | Benedikter, Mathis J. | - |
| dc.contributor.author | Elser, Iris | - |
| dc.contributor.author | Buchmeiser, Michael R. | - |
| dc.contributor.author | Copéret, Christophe | - |
| dc.date.accessioned | 2024-05-28T06:24:50Z | - |
| dc.date.available | 2024-05-28T06:24:50Z | - |
| dc.date.issued | 2020 | de |
| dc.identifier.issn | 1522-2675 | - |
| dc.identifier.issn | 0018-019X | - |
| dc.identifier.other | 1890796832 | - |
| dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-144312 | de |
| dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/14431 | - |
| dc.identifier.uri | http://dx.doi.org/10.18419/opus-14412 | - |
| dc.description.abstract | A well‐defined silica‐supported cationic W imido alkylidene was prepared through surface organometallic chemistry. This catalyst shows preferential activity towards α‐ over internal olefins, which is atypical for W‐based catalysts, but consistent with the strong σ‐donating ability of the NHC ancillary ligand. Complementing the studies on tungsten‐based d0 metathesis catalysts, the silica‐supported cationic W imido alkylidene displays the highest activity among W imido catalysts for α‐olefins and shows improved selectivity for this class of olefins compared to Mo‐based catalysts. | en |
| dc.description.sponsorship | National Research Fund, Luxembourg | de |
| dc.description.sponsorship | ETHZ Postdoctoral Fellowship Program | de |
| dc.description.sponsorship | Marie Curie Actions for People COFUND Program | de |
| dc.description.sponsorship | Deutsche Forschungsgemeinschaft | de |
| dc.description.sponsorship | Projekt DEAL | de |
| dc.language.iso | en | de |
| dc.relation.uri | doi:10.1002/hlca.202000161 | de |
| dc.rights | info:eu-repo/semantics/openAccess | de |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | de |
| dc.subject.ddc | 540 | de |
| dc.title | Silica‐supported cationic tungsten imido alkylidene stabilized by an N‐heterocyclic carbene ligand boosts activity and selectivity in the metathesis of α‐olefins | en |
| dc.type | article | de |
| dc.date.updated | 2023-11-14T05:07:38Z | - |
| ubs.fakultaet | Chemie | de |
| ubs.fakultaet | Fakultätsübergreifend / Sonstige Einrichtung | de |
| ubs.institut | Institut für Polymerchemie | de |
| ubs.institut | Fakultätsübergreifend / Sonstige Einrichtung | de |
| ubs.publikation.seiten | 5 | de |
| ubs.publikation.source | Helvetica chimica acta 103 (2020), No. e2000161 | de |
| ubs.publikation.typ | Zeitschriftenartikel | de |
| Enthalten in den Sammlungen: | 03 Fakultät Chemie | |
Dateien zu dieser Ressource:
| Datei | Beschreibung | Größe | Format | |
|---|---|---|---|---|
| HLCA_HLCA202000161.pdf | 6,54 MB | Adobe PDF | Öffnen/Anzeigen |
Diese Ressource wurde unter folgender Copyright-Bestimmung veröffentlicht: Lizenz von Creative Commons
