Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-2001
Fietz, Walter H.
|Title:||Dioxygenolytic cleavage of aryl ether bonds: 1,2-Dihydro-1,2-dihydroxy-4-carboxybenzophenone as evidence for initial 1,2-dioxygenation in 3- and 4-carboxy biphenyl ether degradation|
|metadata.ubs.publikation.source:||FEMS microbiology letters 69 (1990), S. 317-321. URL http://dx.doi.org./10.1111/j.1574-6968.1990.tb04251.x|
|Abstract:||A bacterial strain, Pseudomonas sp. POB 310, was enriched with 4-carboxy biphenyl ether as sole source of carbon and energy. Resting cells of POB 310 co-oxidize a substrate analogue, 4-carboxybenzophenone, yielding 1,2-dihydro-1,2-dihydroxy-4-carboxy-benzophenone. The ether bond of 3- and 4-carboxy biphenyl ether is cleaved analogously by initial 1,2-dioxygenation, yielding a hemiacetal which is hydrolysed to proto-catechuate and phenol. These intermediates are degraded via an ortho and meta pathway, respectively. Alternative 2,3- and 3,4-dioxygenation can be ruled out as triggering steps in carboxy biphenyl ether degradation.|
|Appears in Collections:||04 Fakultät Energie-, Verfahrens- und Biotechnik|
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