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Authors: Romanenko, Vadim D.
Ruban, Alexander V.
Roshenko, Alexander B.
Povolotskii, Mark I.
Sarina, Tatjana V.
Gudat, Dietrich
Niecke, Edgar
Title: Reactions of iminophosphanes with chlorotris(triphenylphosphine)rhodium(I): generation and NMR identification of the first iminophosphanerhodium(I) and iminophosphanerhodium(III) complexes
Issue Date: 1993 Zeitschriftenartikel Mendeleev communications 3 (1993), S. 7-8. URL
Abstract: Iminophosphanes [RO-P=NAr] (R = Me, 2-MeC6H4; Ar = 2,4,6-Bu'3C6H2) 1a,b react with RhClL3 (L = Ph3P) via ligand exchange to give KP-iminophosphane complexes of rhodium(i) [RhCl(MeOP=NAr)2L] 2 and [PhCl(2-MeC6H4OP=NAr)L2] 3. Under analogous conditions, P-halogenoiminophosphanes [X-P=NAr] (X = Cl, Br, I) 3a–c undergo a facile oxidative addition of the P-X bond, forming five-coordinate iminophosphanerhodium(III) complexes of composition [L2Cl(X)Rh(σ-P=BAr)] 5.
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