Hydrogenic Rydberg atoms in strong magnetic fields: theoretical and experimental spectra in the transition region from regularity to irregularity

Abstract

For deuterium Rydberg atoms in a magnetic field of sim6~T we compare the complete experimental spectrum in the range -190 cm-1 to -20 cm-1 with the positions and oscillator strengths of the corresponding quantum theoretically calculated photoabsorption lines. The agreement is excellent. The range of energy covered extends from the end of thel-mixing regime up to the regions where the approximate integrability of the problem is completely lost, and the corresponding classical system undergoes a transition to chaos.