Organic metals from chiral BEDT-TTF donors

Chen, Ben-ming; Deilacher, Frank; Hoch, Matthias; Keller, Heimo J.; Wu, Pei-ji; Gärtner, Stephan; Kahlich, Siegfried; Schweitzer, Dieter

Organic metals from chiral BEDT-TTF donors

dc.contributor.author	Chen, Ben-ming	de
dc.contributor.author	Deilacher, Frank	de
dc.contributor.author	Hoch, Matthias	de
dc.contributor.author	Keller, Heimo J.	de
dc.contributor.author	Wu, Pei-ji	de
dc.contributor.author	Gärtner, Stephan	de
dc.contributor.author	Kahlich, Siegfried	de
dc.contributor.author	Schweitzer, Dieter	de
dc.date.accessioned	2011-08-08	de
dc.date.accessioned	2016-03-31T08:36:22Z
dc.date.available	2011-08-08	de
dc.date.available	2016-03-31T08:36:22Z
dc.date.issued	1991	de
dc.date.updated	2012-07-16	de
dc.description.abstract	We have shown that is is possible to obtain organic metals from chiral molecules. The X-ray results prove an oxidation number of + 1.5 for the radical cations in at least two cases. To our best knowledge. these are: the first examples of BEDT-TTF-related radical cation salts with this oxidation number. As expected, we obtained statistically disordered crystals, containing the two different enantiomers in a "racemic" mixture. The broad smeared-out phase transitions are probably due to this disorder, or may be caused by the three-dimensional interactions which have been observed, so far, only once in a BEDT-TTF radical salt. We will crystallize the metallic compounds using "optically pure" isomers, in the hope to be able to isolate chiral metals.	en
dc.identifier.other	368198367	de
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-65430	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/5053
dc.identifier.uri	http://dx.doi.org/10.18419/opus-5036
dc.language.iso	en	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.subject.classification	Tetrathiafulvalen , Organischer Supraleiter , Metall , Radikalkationensalz	de
dc.subject.ddc	530	de
dc.title	Organic metals from chiral BEDT-TTF donors	en
dc.type	conferenceObject	de
ubs.fakultaet	Fakultät Mathematik und Physik	de
ubs.fakultaet	Fakultätsübergreifend / Sonstige Einrichtung	de
ubs.institut	3. Physikalisches Institut	de
ubs.institut	Sonstige Einrichtung	de
ubs.opusid	6543	de
ubs.publikation.source	Metzger, Robert M. (Hrsg.): Lower dimensional systems and molecular electronics. New York : Plenum Pr., 1991 (NATO ASI series, B. 248). - ISBN 0-306-43826-7, S. 175-180	de
ubs.publikation.typ	Konferenzbeitrag	de

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