Diastereospecific enantiodivergent allylation of pyrazolones as an entry to β‐aminoamides
| dc.contributor.author | Wannenmacher, Nick | |
| dc.contributor.author | Heberle, Martin | |
| dc.contributor.author | Yu, Xin | |
| dc.contributor.author | Demircan, Aysegül | |
| dc.contributor.author | Wanner, Daniel M. | |
| dc.contributor.author | Pfeffer, Camilla | |
| dc.contributor.author | Peters, René | |
| dc.date.accessioned | 2024-08-13T14:53:01Z | |
| dc.date.available | 2024-08-13T14:53:01Z | |
| dc.date.issued | 2022 | de |
| dc.date.updated | 2023-11-14T00:09:33Z | |
| dc.description.abstract | A diastereospecific enantiodivergent allylation of pyrazolones is reported which is catalyzed by a planar chiral pentaphenylferrocene based palladacycle. With the same catalyst batch both product enantiomers were selectively available. The method is applicable to structurally diverse substrates and gave products with enantiomeric excesses between 85 and 94%. In addition, we could show that pyrazolones are transformable into β‐aminoamides. | en |
| dc.description.sponsorship | China Scholarship Council (CSC) | de |
| dc.description.sponsorship | analytical service of the Institute of Organic Chemistry at the University of Stuttgart | de |
| dc.identifier.issn | 1615-4169 | |
| dc.identifier.other | 1898542473 | |
| dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-148280 | de |
| dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/14828 | |
| dc.identifier.uri | http://dx.doi.org/10.18419/opus-14809 | |
| dc.language.iso | en | de |
| dc.relation.uri | doi:10.1002/adsc.202200185 | de |
| dc.rights | info:eu-repo/semantics/openAccess | de |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | de |
| dc.subject.ddc | 540 | de |
| dc.title | Diastereospecific enantiodivergent allylation of pyrazolones as an entry to β‐aminoamides | en |
| dc.type | article | de |
| ubs.fakultaet | Chemie | de |
| ubs.institut | Institut für Organische Chemie | de |
| ubs.publikation.seiten | 3396-3403 | de |
| ubs.publikation.source | Advanced synthesis & catalysis 364 (2022), S. 3396-3403 | de |
| ubs.publikation.typ | Zeitschriftenartikel | de |