Intramolecular charge transfer in ruthenium complexes [Ru(acac)2(ciq)] with ambidentate camphoriminoquinone (ciq) ligands

Filippou, Vasileios; Blickle, Svenja; Bubrin, Martina; Kaim, Wolfgang

Intramolecular charge transfer in ruthenium complexes [Ru(acac)2(ciq)] with ambidentate camphoriminoquinone (ciq) ligands

dc.contributor.author	Filippou, Vasileios
dc.contributor.author	Blickle, Svenja
dc.contributor.author	Bubrin, Martina
dc.contributor.author	Kaim, Wolfgang
dc.date.accessioned	2024-08-21T08:05:14Z
dc.date.available	2024-08-21T08:05:14Z
dc.date.issued	2021	de
dc.date.updated	2023-11-14T02:57:42Z
dc.description.abstract	Reaction of [Ru(acac)2(MeCN)2], acac−=acetylacetonate, with N‐phenylcamphoriminoquinone (pciq) or the new N‐(2‐thiomethylphenyl)‐camphoriminoquinone (tciq) produces complexes [Ru(acac)2(pciq)] and [Ru(acac)2(tciq)] with N,O or N,S coordination and E or Z configuration at the C=N bond, respectively. Oxidation state assignments in comparison with classical iminoquinone ligands are based on structural data in connection with DFT calculations. Reversible oxidation yields complex ions [RuIII(acac)2(pciq)]+ and [RuIII(acac)2(tciq)]+ as characterized by EPR, IR and UV‐vis‐NIR spectroelectrochemistry.	en
dc.description.sponsorship	state of Baden-Württemberg	de
dc.description.sponsorship	bwHPC	de
dc.description.sponsorship	DFG	de
dc.identifier.issn	1521-3749
dc.identifier.issn	0044-2313
dc.identifier.other	1899379053
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-148685	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/14868
dc.identifier.uri	http://dx.doi.org/10.18419/opus-14849
dc.language.iso	en	de
dc.relation.uri	doi:10.1002/zaac.202000464	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/	de
dc.subject.ddc	540	de
dc.title	Intramolecular charge transfer in ruthenium complexes [Ru(acac)2(ciq)] with ambidentate camphoriminoquinone (ciq) ligands	en
dc.type	article	de
ubs.fakultaet	Chemie	de
ubs.institut	Institut für Anorganische Chemie	de
ubs.publikation.seiten	525-533	de
ubs.publikation.source	Zeitschrift für anorganische und allgemeine Chemie 647 (2021), S. 525-533	de
ubs.publikation.typ	Zeitschriftenartikel	de

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