Weller, FrankPauls, IreneDehnicke, KurtBecker, Gerd2010-11-172016-03-312010-11-172016-03-311991340368039http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-58269http://elib.uni-stuttgart.de/handle/11682/7408http://dx.doi.org/10.18419/opus-7391The reaction of tungsten hexachloride with excess 2,2-dimethylpropylidynephosphane, C 4 H 9-C≡P, leads to the tungsten phosphaalkyne clusters WCI 5 P 2(C 5 H 9) 3 and WCI 4 P 5(C 5 H 9) as well as to the tris(t-butyl)cyclopropenium pentachloro tungsten alkyne complex {C 3(C 4 H 9) 3] + (WCI 5(C 4 H 9C≡CC 4 H )]-. All complexes were characterized by X-ray structure determinations.deinfo:eu-repo/semantics/openAccessWolframhexachlorid , Kristallstruktur540Die Reaktionen von Wolframhexachlorid mit überschüssigem 2,2-Dimethylpropylidinphosphan : die Kristallstrukturen von WCl5P2(C5H9)3, WCl4P5(C5H9)5 und [C3(C4H9)3]+[WCl5(C4H9C≡CC4H9]-The reactions of tungsten hexachloride with excess 2,2-dimethylpropylidynephosphane : the crystal structures of WCl5P2(C5H9)3, WCl4P5(C5H9)5 und [C3(C4H9)3]+[WCl5(C4H9C≡CC4H9]-article2011-05-17