Mollère, Phillip D.Bock, HansBecker, GerdFritz, Gerhard2010-10-192016-03-312010-10-192016-03-311973348344457http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-57217http://elib.uni-stuttgart.de/handle/11682/7402http://dx.doi.org/10.18419/opus-7385The photoelectron spectra of methyl and silyl sulfides are assigned on the basis of modified CNDO-SCF-MO calculations. The orbital sequence (2b1, 4a1, 3b2) is found to be independent of conformation. The static geometry of the sulfides is in keeping with a smaller charge shift to sulfur accompanying the carbon-silicon exchange. Comparison of the results wit those of the analogous ethers lends support to the previous assignment of the latter.eninfo:eu-repo/semantics/openAccessPhotoelektronenspektroskopie , Sulfide540article