Becker, GerdSchmidt, HelmutUhl, GudrunUhl, Werner2010-12-202016-03-312010-12-202016-03-311990343300559http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-58230http://elib.uni-stuttgart.de/handle/11682/1314http://dx.doi.org/10.18419/opus-1297Tris(trimethylsilyl)phosphine and its more reactive derivative lithium bis(trimethylsilyl)phosphide·2tetrahydrofuran are very useful reagents for the preparation of compounds with a single or a multiple element phosphorus bond. They react readily with various element halides, with carboxylic acid chlorides, and with carboxylic esters, as well as with other organic electrophiles via a substitution of lithium and/or a cleavage of the weak polar Si-P bonds.eninfo:eu-repo/semantics/openAccessPhosphine , Lithiumphosphide540article