Welzel, StefanZander, ChristianNieken, Ulrich2023-10-182023-10-1820230009-286X1522-26401869937481http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-136541http://elib.uni-stuttgart.de/handle/11682/13654http://dx.doi.org/10.18419/opus-13635Polymer fouling is a major problem for the operation of continuous reactors. Therefore, it is important to understand and quantitatively describe the mechanisms leading to formation of fouling deposits. In this work, a CFD model for the radical polymerization of N-vinylpyrrolidone is presented, where the reaction kinetics, a viscosity model, and a transport model for polymer moments are determined from independent experiments. The model is compared to experimental obtained residence time distributions in capillary reactors over a wide range of concentrations. Model predictions are in good agreement with experimental findings.eninfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/4.0/540Wall layer formation in continuously operated tubular reactors for freeāradical polymerizationsarticle2023-07-11