Schilbach, WolfgangGönna, Volker von derGudat, DietrichNieger, MartinNiecke, Edgar2012-05-162016-03-312012-05-162016-03-311994370185897http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-74070http://elib.uni-stuttgart.de/handle/11682/7971http://dx.doi.org/10.18419/opus-7954Interesting trapping products with phosphanes and chlorotrimethylsilane result from reactions with the novel intermediate phosphoranylidene carbenoid 1: These lead to the phosphoniomethanide 2 with PPh3, the dihydrodiphosphete 3 with PMe3, and the imino(methylene)phosphorane 4 with ClSiMe3. R = 2,4,6-tBu3C6H2, R′ = Ph, Me.eninfo:eu-repo/semantics/openAccessCarbenoide , Iminophosphorane540article2014-09-26