(2,2,8,8-tetramethyl-5-oxa-4,6-diphospha-3,6-nonadiene)tetrakis[dicarbonyl(methylcyclopentadienyl)manganese], the first complexed bis(phosphavinyl) ether

Ziegler, Manfred L.Balles, RainerNuber, BerndBecker, GerdSchmidt, HelmutKanellakopulos, BasilPowietzka, Bernhard2010-12-202016-03-312010-12-202016-03-311987343219352http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-58192http://elib.uni-stuttgart.de/handle/11682/7418http://dx.doi.org/10.18419/opus-7401The title compound 1 is the complex of a novel ligand. It is formed from [(CH3C5H4)Mn(CO)2·thf] and (CH3)3C-C=P, presumably with uptake of H2O. The bis(phosphavinyl) ether in 1 functions as an 8-electron donor toward the four (CH3C5H4)Mn(CO)2 units (abbreviated here as Mn).eninfo:eu-repo/semantics/openAccessPhosphorverbindungen540(2,2,8,8-tetramethyl-5-oxa-4,6-diphospha-3,6-nonadiene)tetrakis[dicarbonyl(methylcyclopentadienyl)manganese], the first complexed bis(phosphavinyl) etherarticle2014-09-26