Activation of aromatic C-F bonds by a N‐heterocyclic olefin (NHO)

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2020

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Mandal, Debdeep
Chandra, Shubhadeep
Neuman, Nicolás I.
Mahata, Alok
Sarkar, Arighna
Kundu, Abhinanda
Anga, Srinivas
Rawat, Hemant
Schulzke, Carola
Mote, Kaustubh R.

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Abstract

A N‐heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C-F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl‐substituted alkenes in which the central carbon-carbon double bond is in a twisted geometry.

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