Photoelectron spectra and molecular properties. 20, Dimethyl ether, methoxysilane, and disiloxane

Abstract

The photoelectron (PE) spectra of methyl and silyl ethers are assigned and correlated on the basis of CNDO/2-SCF-MO calculations. The dynamic behavior of the individual orbitals is discussed in terms of electronic and geometric perturbations of the ether system.