Browsing by Author "Benincori, Tiziana"

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    In situ electrochemical investigations of inherently chiral 2,2′‐biindole architectures with oligothiophene terminals
    (2021) Malacrida, Claudia; Scapinello, Luca; Cirilli, Roberto; Grecchi, Sara; Penoni, Andrea; Benincori, Tiziana; Ludwigs, Sabine
    The synthesis and characterization of three new inherently chiral N,N′‐dipropyl‐3,3′‐diheteroaryl‐2,2′‐biindole monomers, nicknamed Ind2T4, Ind2T6 and Ind2Ph2T4, which differ in the number of thiophenes as terminals, are reported. In addition to a full monomer characterization, stable electroactive oligomeric films were obtained by electro‐oxidation upon cycling to potentials which activate the thiophene terminals. Cyclic voltammetry, UV‐Vis‐NIR spectroelectrochemistry and in situ conductance measurements show that oligomeric films of Ind2T6 present the best stability and electrochromic switching performance. Enantioselective tests with a chiral ferrocene amine clearly show the potential as chiral selectors for analytical and sensing purposes.