Browsing by Author "Effenberger, Franz X."

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    Konformation und Lichtabsorption von (2-Alkoxyvinyl)ethandionen (Chromophore Systeme ; 2)
    (1991) Effenberger, Franz X.; Kramme, Roland; Lindner, Hans Jörg; Martin, Georg; Martin, Hans-Dieter; Mayer, Bernhard
    The unusual color properties of yellow 1,2-bis(4,5-dihydrofuran-3-yl)ethane-1,2-dione (1) and colorless 1,2-bis(5,6-dihydro-4H-pyran-3-yl)ethane-1,2-dione (2) in the solid state and in solution are investigated by crystal structure analysis, UV-Vis, PE, and 13C-NMR spectroscopy as well as by reparameterized force-field calculations. Dione 1 takes an antiperiplaner CO/CO conformation of its chromophore in the solid state whereas dione 2 is twisted in this respect by 102°. In solution both chromophores are not planar, but 1 is less distorted (ca. 142°) than dione 2 (ca. 126°). The calculated rotational barrier for CO/CO twisting amounts to 0.9 kcal mol-1 for 1 and to 2.2 kcal mol-1 for 2.