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Browsing by Author "Nuber, Bernd"

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    (2, 2, 8, 8-Tetramethyl-5-oxa-4,6-diphospha-3, 6-nonadien)tetrakis[dicarbonyl-(methylcyclopentadienyl)mangan], der erste komplexierte Bis(phosphavinyl)ether
    (1987) Ziegler, Manfred L.; Balles, Rainer; Nuber, Bernd; Becker, Gerd; Schmidt, Helmut; Kanellakopulos, Basil; Powietzka, Bernhard
    Der Komplex eines neuartigen Liganden ist die Titelverbindung 1. Sie entsteht aus [(CH3C5H4)Mn(CO)2·thf] und (CH3)3C-C=P vermutlich unter H2O-Aufnahme. Im paramagnetischen Komplex 1 fungiert der Bis(phosphavinyl)ether als 8-Elektronendonor gegenüber den vier (CH3C5H4)Mn(CO)2-Einheiten.
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    (2,2,8,8-tetramethyl-5-oxa-4,6-diphospha-3,6-nonadiene)tetrakis[dicarbonyl(methylcyclopentadienyl)manganese], the first complexed bis(phosphavinyl) ether
    (1987) Ziegler, Manfred L.; Balles, Rainer; Nuber, Bernd; Becker, Gerd; Schmidt, Helmut; Kanellakopulos, Basil; Powietzka, Bernhard
    The title compound 1 is the complex of a novel ligand. It is formed from [(CH3C5H4)Mn(CO)2·thf] and (CH3)3C-C=P, presumably with uptake of H2O. The bis(phosphavinyl) ether in 1 functions as an 8-electron donor toward the four (CH3C5H4)Mn(CO)2 units (abbreviated here as Mn).
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