Browsing by Author "Ruth, Paul Niklas"

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    Linear and bent Cp*2Si : reversible phase transition of a key molecule
    (2023) Ruth, Paul Niklas; Sarcevic, Julijan; Herbst‐Irmer, Regine; Sindlinger, Christian P.; Stalke, Dietmar
    The solid-state structure of decamethylsilicocene Cp*2Si with a bent and a linear molecule in the same unit cell was so far considered an exception in relation to the structures of its all-bent heavier analogues Cp*2E with E=Ge, Sn, Pb. Here, we present the solution to this conundrum by reporting a low-temperature phase, where all three symmetrically independent molecules are present in a bent formation. This reversible enantiotropic phase transition occurs in the temperature range between 80 K and 130 K and provides a rationale for the unexpected linear molecule based in entropy beyond hand-waving explanations such as electronic reasons or packing effects.