Browsing by Author "Schubert, Markus"

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    Degradation rate location dependency of photovoltaic systems
    (2020) Frick, Alexander; Makrides, George; Schubert, Markus; Schlecht, Matthias; Georghiou, George E.
    A main challenge towards ensuring improved lifetime performance and reduction of financial risks of photovoltaic (PV) technologies remains the accurate degradation quantification of field systems and the dependency of this performance loss rate to climatic conditions. The purpose of this study is to address these technological issues by presenting a unified methodology for accurately calculating the degradation rate (𝑅𝐷) of PV systems and provide evidence that degradation mechanisms are location dependent. The method followed included the application of data inference and time series analytics, in the scope of comparing the long-term 𝑅𝐷 of different crystalline Silicon (c-Si) PV systems, installed at different climatic locations. The application of data quality and filtering steps ensured data fidelity for the 𝑅𝐷 analysis. The yearly 𝑅𝐷 results demonstrated that the adopted time series analytical techniques converged after 7 years and were in close agreement to the degradation results obtained from indoor standardized procedures. Finally, the initial hypothesis that the 𝑅𝐷 is location dependent was verified, since the multicrystalline silicon (multi-c-Si) systems at the warm climatic region exhibited higher degradation compared to the respective systems at the moderate climate. For the investigated monocrystalline silicon (mono-c-Si) systems the location-dependency is also affected by the manufacturing technology.
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    Fourier spotting : a novel setup for single-color reflectometry
    (2022) Siegel, Johannes; Berner, Marcel; Werner, Jürgen H.; Proll, Günther; Fechner, Peter; Schubert, Markus
    Single-color reflectrometry is a sensitive and robust detection method in optical biosensor applications, for example for bioanalysis. It is based on the interference of reflected monochromatic radiation and is label free. We present a novel setup for single-color reflectometry based on the patented technology of Berner et al. from 2016. Tilting areas of micro-mirrors allow us to encode the optical reflection signal of an analyte and reference channel into a particular carrier frequency with the amplitude being proportional to the local reflection. Therefore, a single photodiode is sufficient to collect the signals from both channels simultaneously. A 180∘ phase shift in the tilt frequency of two calibrated micro-mirror areas leads to a superposition of the analyte and reference signal which enables an efficient reduction of the baseline offset and potential baseline offset drift. A performance test reveals that we are able to detect changes of the refractive index n down to Δn < 0.01 of saline solutions as regents. A further test validates the detection of heterogeneous binding interaction. This test compromises immobilized testosterone-bovine serum albumin on a three-dimensional layer of biopolymer as ligand and monoclonal anti-testosterone antibodies as analyte. Antibody/antigen binding induces a local growth of the biolayer and change in the refractive index, which is measured via the local change of the reflection. Reproducible measurements enable for the analysis of the binding kinetics by determining the affinity constant KA = 1.59 × 10- 7 M- 1. In summary, this work shows that the concept of differential Fourier spotting as novel setup for single-color reflectometry is suitable for reliable bioanalysis.Graphical Abstract