Darstellung und Reaktionen von Tricarbonyl-(trimethylsiloxy-1,3-cyclohexadien)-Eisen-Komplexen

Abstract

Tricarbonyl (trimethylsiloxy-1,3-cyclohexadien) iron complexes react with triphenylmethyl tetrafluoroborate by elimination of both, hydride and the trimethylsilyl group. The tricarbonyl(1,3cyclohexadienyl)iron salt, resulting from hydrolysis, reacts with nucleophiles to afford 5-substituted tricarbonyl(2-hydroxy-1,3-cyclohexadien)-iron complexes.