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Authors: Effenberger, Franz
Niesert, Claus-Peter
Title: Herstellung konjugierter Polyene mit Anthryl- und N-Methylpyridinium-Endgruppen
Other Titles: Preparation of conjugated polyenes with anthryl and N-nethylpyridinium terminal groups
Issue Date: 1992 Zeitschriftenartikel Synthesis (1992), S. 1137-1144. URL
Abstract: The synthesis of terminally donor-acceptor substituted polyenes from the respective aldehydes via Horner reactions is described. As donor group the 9-anthryl and as acceptor moiety the 4-(N-methyl)pyridinium residue were chosen. A bicyclo[2.2.2]octane unit was incorporated into the chain to interrupt the conjugation. The separation and characterization of the mixtures of Z/E- isomers obtained in the syntheses was possible.
Appears in Collections:03 Fakultät Chemie

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