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Authors: Eigenberger, Gerhart
Title: Kinetic instabilities in heterogeneously catalyzed reactions. Pt. 1, Rate multiplicity with Langmuir-type kinetics
Issue Date: 1978 Zeitschriftenartikel Chemical Engineering Science 33 (1978), S. 1255-1261
Abstract: This paper is concerned with the occurrence of rate multiplicities (ignition-extinction phenomena). It is shown that rate multiplicity can be caused by the competing chemisorption of A and B upon the same active sites of the catalyst. Rate multiplicity can occur if at least one of the chemisorption or reaction steps is of second order. No rate multiplicity can be expected, if either A or B reacts via an Eley-Rideal type mechanism.
Appears in Collections:07 Fakultät Konstruktions-, Produktions- und Fahrzeugtechnik

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