Please use this identifier to cite or link to this item:
Authors: Mollère, Phillip D.
Bock, Hans
Becker, Gerd
Fritz, Gerhard
Title: Photoelectron spectra and molecular properties. 21, Dimethyl sulfide, methyl silyl sulfide, and disilyl sulfide
Issue Date: 1973 Zeitschriftenartikel Journal of organometallic chemistry 61 (1973), S. 127-132. URL
Abstract: The photoelectron spectra of methyl and silyl sulfides are assigned on the basis of modified CNDO-SCF-MO calculations. The orbital sequence (2b1, 4a1, 3b2) is found to be independent of conformation. The static geometry of the sulfides is in keeping with a smaller charge shift to sulfur accompanying the carbon-silicon exchange. Comparison of the results wit those of the analogous ethers lends support to the previous assignment of the latter.
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

Files in This Item:
File Description SizeFormat 
bec9.pdf224,24 kBAdobe PDFView/Open

Items in OPUS are protected by copyright, with all rights reserved, unless otherwise indicated.