Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-7385
Authors: Mollère, Phillip D.
Bock, Hans
Becker, Gerd
Fritz, Gerhard
Title: Photoelectron spectra and molecular properties. 21, Dimethyl sulfide, methyl silyl sulfide, and disilyl sulfide
Issue Date: 1973
metadata.ubs.publikation.typ: Zeitschriftenartikel
metadata.ubs.publikation.source: Journal of organometallic chemistry 61 (1973), S. 127-132. URL http://dx.doi.org./10.1016/S0022-328X(00)86541-9
URI: http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-57217
http://elib.uni-stuttgart.de/handle/11682/7402
http://dx.doi.org/10.18419/opus-7385
Abstract: The photoelectron spectra of methyl and silyl sulfides are assigned on the basis of modified CNDO-SCF-MO calculations. The orbital sequence (2b1, 4a1, 3b2) is found to be independent of conformation. The static geometry of the sulfides is in keeping with a smaller charge shift to sulfur accompanying the carbon-silicon exchange. Comparison of the results wit those of the analogous ethers lends support to the previous assignment of the latter.
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

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