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Authors: Becker, Gerd
Gresser, Gudrun
Uhl, Werner
Title: 2,2-Dimethylpropylidinphosphan, eine stabile Verbindung mit einem Phosphoratom der Koordinationszahl 1 (Acyl- und Alkylidenphosphane ; 15)
Other Titles: 2,2 dimethylpropylidynephosphine, a stable compound wlth a phosphorus atom of coordination number 1 (Acyl- and Alkylidenephosphines ; 15)
Issue Date: 1981 Zeitschriftenartikel Zeitschrift für Naturforschung B 36 (1981), S. 16-19
Abstract: In the presence of small amounts of solid sodium hydroxide, (2,2-dimethyl-1-(trimethyl-siloxy)propylidene]-trimethylsilylphosphine reacts at + 20° C to give hexamethydisiloxane and 2,2-dimethylpropylidynephosphine (2). In contrast to similar alkylidynephosphines this compound is stabIe at room temperature. The IR and mass spectrum are discussed, and 1 H, 13 C and 31 PNMR spectral data are given.
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

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