Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-7531
Authors: Spiess, Hans Wolfgang
Schweitzer, Dieter
Haeberlen, Ulrich
Hausser, Karl H.
Title: Spin rotation interaction and anisotropic chemical shift in 13CS2
Issue Date: 1971
metadata.ubs.publikation.typ: Zeitschriftenartikel
metadata.ubs.publikation.source: Journal of magnetic resonance 5 (1971), S. 101-108. URL http://dx.doi.org./10.1016/0022-2364(71)90068-0
URI: http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-63653
http://elib.uni-stuttgart.de/handle/11682/7548
http://dx.doi.org/10.18419/opus-7531
Abstract: The 13C nuclear spin-lattice relaxation time T1 was studied in liquid CS2 from -106°C to +35°C at resonance frequencies of 14, 30, and 62 MHz. The relaxation is caused by anisotropic chemical shift and spin-rotation interaction. It is shown that for linear molecules the spin-rotation constant C and the anisotropy of the chemical shift Δσ can be obtained from the relaxation rates without use of adjustable parameters. The analysis yields: C = -13.8 ± 1.4 kHz and Δσ = 438 ± 44 ppm.
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

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