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http://dx.doi.org/10.18419/opus-7552
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DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Ippen, Joachim | de |
dc.contributor.author | Chu, Tao-pen | de |
dc.contributor.author | Starker, Barbara | de |
dc.contributor.author | Schweitzer, Dieter | de |
dc.contributor.author | Staab, Heinz A. | de |
dc.date.accessioned | 2011-07-18 | de |
dc.date.accessioned | 2016-03-31T11:43:32Z | - |
dc.date.available | 2011-07-18 | de |
dc.date.available | 2016-03-31T11:43:32Z | - |
dc.date.issued | 1980 | de |
dc.identifier.other | 350482268 | de |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-63938 | de |
dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/7569 | - |
dc.identifier.uri | http://dx.doi.org/10.18419/opus-7552 | - |
dc.description.abstract | In the "metallic" conducting 1:1 complex of tetrathiafulvalene (TTF) and tetracyanoquinodimethane (TCNQ), donor and acceptor molecules form separate stacks in the crystal. In order to enforce other TTF/TCNQ arrangements by altering the molecular architecture the phane-like bridged TTF-paracyclophanes (1), n = 3, and (2) were first synthesized. To do this a novel reaction sequence had to be developed which also facilitated synthesis of the tetrathiafulvalenophanes (3)/(4) (and the corresponding [2.2]-derivatives). (3)/(4) and TCNQ form a 1:4 complex having a conductivity of σ = 5 × 10−3 to 10−2 [Ω cm]−1 (single crystal, long axis, 300 K). | en |
dc.language.iso | en | de |
dc.rights | info:eu-repo/semantics/openAccess | de |
dc.subject.classification | Charge-transfer-Komplexe , Kristallgitter | de |
dc.subject.ddc | 530 | de |
dc.title | [2.2]- and [3.3]tetrathiafulvalenophanes | en |
dc.type | article | de |
ubs.fakultaet | Fakultätsübergreifend / Sonstige Einrichtung | de |
ubs.institut | Sonstige Einrichtung | de |
ubs.opusid | 6393 | de |
ubs.publikation.source | Angewandte Chemie, International edition 19 (1980), S. 67-69. URL http://dx.doi.org./10.1002/anie.198000671 | de |
ubs.publikation.typ | Zeitschriftenartikel | de |
Enthalten in den Sammlungen: | 15 Fakultätsübergreifend / Sonstige Einrichtung |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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schw29_2.pdf | 283,6 kB | Adobe PDF | Öffnen/Anzeigen |
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