Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-7560
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dc.contributor.authorEndres, Helmutde
dc.contributor.authorKeller, Heimo J.de
dc.contributor.authorQueckbörner, Jobst G.de
dc.contributor.authorVeigel, Jürgende
dc.contributor.authorSchweitzer, Dieterde
dc.date.accessioned2011-07-19de
dc.date.accessioned2016-03-31T11:43:33Z-
dc.date.available2011-07-19de
dc.date.available2016-03-31T11:43:33Z-
dc.date.issued1982de
dc.identifier.other350669384de
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-64065de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/7577-
dc.identifier.urihttp://dx.doi.org/10.18419/opus-7560-
dc.description.abstractThe donors TTA and TSA were prepared starting from 1.5-dichloro-9.10-anthracenedione which was converted into 1.5.9.10-tetrachloroan-thracene (TCA) by two alternating chlorination and elimination steps. TCA was reacted under a dry argon atmosphere with suspensions of Na2S2 and Na2Se2 to yield TTA and TSA, respectively. Action of elemental iodine gives highly conductive polyiodides of both donors. Single crystals of TSA·I1.2 actually behave metallic between 220 and 300 K. The X-ray structure of TSA and TSA·I1.2 allows a comparison of intermolecular distances in the neutral and the partially oxidized, ionic stacks of the donor.en
dc.language.isoende
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationCharge-transfer-Komplexe , Metallde
dc.subject.ddc530de
dc.titleThe preparation of new metallic charge-transfer complexes: anthra [9.1-cd:10.5-c'd'] bis [1.2] dithiol (TTA), -diselenol (TSA) and their polyiodidesen
dc.typearticlede
ubs.fakultaetFakultätsübergreifend / Sonstige Einrichtungde
ubs.institutSonstige Einrichtungde
ubs.opusid6406de
ubs.publikation.sourceMolecular crystals and liquid crystals 86 (1982), S. 111-122. URL http://dx.doi.org./10.1080/00268948208073674de
ubs.publikation.typZeitschriftenartikelde
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

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