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dc.contributor.authorYersin, Hartmutde
dc.contributor.authorGallhuber, Erichde
dc.contributor.authorHensler, Geroldde
dc.contributor.authorSchweitzer, Dieterde
dc.date.accessioned2011-08-04de
dc.date.accessioned2016-03-31T11:43:49Z-
dc.date.available2011-08-04de
dc.date.available2016-03-31T11:43:49Z-
dc.date.issued1989de
dc.identifier.other353629197de
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-65257de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/7675-
dc.identifier.urihttp://dx.doi.org/10.18419/opus-7658-
dc.description.abstractFor the title compounds zero-magnetic field ODMR signals have been observed on the zero-phonon lines which correspond to the two lowest excited states and which result from Ru4d→bpyπ* charge-transfer transitions. The splitting into sublevels are of the order of 0.1 cm−1 and the corresponding electronic states may be classified as doubly degenerate on the basis of the usual resolution of the optical emission spectra. Several microwave resonances are detected and assigned to different sites of the [Ru(bpy)3]2+ chromophores. Small relaxation rates between the sublevels (compared to other excited-state deactivation rates) are found to be important for a description of the spectroscopic properties at low temperatures.en
dc.language.isoende
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationODMR-Spektroskopie , Bipyridinede
dc.subject.ddc530de
dc.titleZero-field splittings of the two lowest excited electronic states in crystalline [Ru(bpy)3]X2 with X=PF6, ClO4en
dc.typearticlede
ubs.fakultaetFakultätsübergreifend / Sonstige Einrichtungde
ubs.fakultaetFakultät Mathematik und Physikde
ubs.institutSonstige Einrichtungde
ubs.institut3. Physikalisches Institutde
ubs.opusid6525de
ubs.publikation.sourceChemical physics letters 161 (1989), S. 315-320. URL http://dx.doi.org.10.1016/0009-2614(89)85091-2de
ubs.publikation.typZeitschriftenartikelde
Enthalten in den Sammlungen:15 Fakultätsübergreifend / Sonstige Einrichtung

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