Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-7958
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dc.contributor.authorRomanenko, Vadim D.de
dc.contributor.authorRuban, Alexander V.de
dc.contributor.authorRoshenko, Alexander B.de
dc.contributor.authorPovolotskii, Mark I.de
dc.contributor.authorSarina, Tatjana V.de
dc.contributor.authorGudat, Dietrichde
dc.contributor.authorNiecke, Edgarde
dc.date.accessioned2012-05-24de
dc.date.accessioned2016-03-31T11:44:45Z-
dc.date.available2012-05-24de
dc.date.available2016-03-31T11:44:45Z-
dc.date.issued1993de
dc.identifier.other370348370de
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-74321de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/7975-
dc.identifier.urihttp://dx.doi.org/10.18419/opus-7958-
dc.description.abstractIminophosphanes [RO-P=NAr] (R = Me, 2-MeC6H4; Ar = 2,4,6-Bu'3C6H2) 1a,b react with RhClL3 (L = Ph3P) via ligand exchange to give KP-iminophosphane complexes of rhodium(i) [RhCl(MeOP=NAr)2L] 2 and [PhCl(2-MeC6H4OP=NAr)L2] 3. Under analogous conditions, P-halogenoiminophosphanes [X-P=NAr] (X = Cl, Br, I) 3a–c undergo a facile oxidative addition of the P-X bond, forming five-coordinate iminophosphanerhodium(III) complexes of composition [L2Cl(X)Rh(σ-P=BAr)] 5.en
dc.language.isoende
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationIminophosphane , NMR-Spektroskopiede
dc.subject.ddc540de
dc.titleReactions of iminophosphanes with chlorotris(triphenylphosphine)rhodium(I): generation and NMR identification of the first iminophosphanerhodium(I) and iminophosphanerhodium(III) complexesen
dc.typearticlede
ubs.fakultaetFakultätsübergreifend / Sonstige Einrichtungde
ubs.institutSonstige Einrichtungde
ubs.opusid7432de
ubs.publikation.sourceMendeleev communications 3 (1993), S. 7-8. URL http://dx.doi.org/10.1070/MC1993v003n01ABEH000194de
ubs.publikation.typZeitschriftenartikelde
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

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