Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-7974
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dc.contributor.authorGudat, Dietrichde
dc.contributor.authorNiecke, Edgarde
dc.date.accessioned2012-05-24de
dc.date.accessioned2016-03-31T11:44:48Z-
dc.date.available2012-05-24de
dc.date.available2016-03-31T11:44:48Z-
dc.date.issued1987de
dc.identifier.other37060430Xde
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-74490de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/7991-
dc.identifier.urihttp://dx.doi.org/10.18419/opus-7974-
dc.description.abstractReaction of (Me5C5)P=NBut with [(R3P)2Ni(cod)](cod = cyclo-octa-1,5-diene)(R = Et, Bu, or Ph) produces complexes [(R3P)2Ni(C5Me5)P=NBut], which rearrange to yield the novel metal-substituted iminophosphanes, [(R3P)(η5-C5Me5)Ni–P=NBut] and free phosphane R3P, the new complexes being identified by means of n.m.r. spectroscopy; similarly, the metallophospha-alkenes, [(R3P)(η5-C5Me5)Ni–P=C(SiMe3)2] are formed via reaction of (Me5C5)P=C(SiMe3)2 and [(R3P)Ni(alkene)2].en
dc.language.isoende
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationIminophosphane , Metallkomplexe , NMR-Spektroskopiede
dc.subject.ddc540de
dc.titleTransfer of a pentamethylcyclopentadienyl ligand from phosphorus to nickel: generation and spectroscopic characterization of the first examples of metalloiminophosphanes [(η5-Me5C5)(R3P)Ni-P=NBut](R = Et, Bu, or Ph)en
dc.typearticlede
ubs.fakultaetFakultätsübergreifend / Sonstige Einrichtungde
ubs.institutSonstige Einrichtungde
ubs.opusid7449de
ubs.publikation.sourceJournal of the Chemical Society, Chemical communications (1987), S. 10-11. URL http://dx.doi.org./10.1039/C39870000010de
ubs.publikation.typZeitschriftenartikelde
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

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