Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-7978
Authors: Gudat, Dietrich
Niecke, Edgar
Krebs, Bernt
Dartmann, Mechtild
Title: Reaction of (pentamethylcyclopentadienyl)(tert-butylimino)-phosphane with tris(acetonitrile)tricarbonylmolybdenum(0): evidence for a metalloiminophosphane intermediate
Issue Date: 1986
metadata.ubs.publikation.typ: Zeitschriftenartikel
metadata.ubs.publikation.source: Organometallics 5 (1986), S. 2376-2377. URL http://dx.doi.org./10.1021/om00142a034
URI: http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-74583
http://elib.uni-stuttgart.de/handle/11682/7995
http://dx.doi.org/10.18419/opus-7978
Abstract: (η1-Me5C5)P=N(t-Bu) (1) was prepared in a two-step synthesis from Me5C5PCl2. Reaction of 1 with (MeCN)3Mo(CO)3 affords the spirocyclic compound (η1-Me5C5PN(t-Bu)PN(T-Bu)C(O)Mo(CO)2(η5-C5Me5) (5), whose structure was determined by x-ray crystallography. A metalloiminophosphine, (η5-Me5C5)(CO)3MoP=N(t-Bu) (7), is proposed to be the key intermediate in the formation of 5.
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