Please use this identifier to cite or link to this item:
Authors: Gudat, Dietrich
Niecke, Edgar
Arif, Atta M.
Cowley, Alan H.
Quashie, Sapé
Title: Synthesis of a phosphavinyl complex via shift of a pentamethylcyclopentadienyl from phosphorus to iron
Issue Date: 1986 Zeitschriftenartikel Organometallics 5 (1986), S. 593-595. URL
Abstract: The reaction of the phosphaalkene (μ1-Me5C5)P=C(SiMe3)2 with Fe2(CO)9 affords the μ1 (P-bonded) complex (μ1-Me5C5)[(CO)4Fe]P=C(SiMe3)2 (4). Photolysis of 4 produces the phosphavinyl complex [Fe-{μ1-P=C(SiMe3)2}(η5-Me5C5)(CO)2] (5). Compound 5 can also be prepared via the metathetical reaction of (Me3Si)2C=PCl with K[Fe(η5-Me5C5)(CO)2]. The structure of 5 has been determined by X-ray crystallography.
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

Files in This Item:
File Description SizeFormat 
gud25.pdf499,78 kBAdobe PDFView/Open

Items in OPUS are protected by copyright, with all rights reserved, unless otherwise indicated.