Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-7982
Authors: Gudat, Dietrich
Niecke, Edgar
Arif, Atta M.
Cowley, Alan H.
Quashie, Sapé
Title: Synthesis of a phosphavinyl complex via shift of a pentamethylcyclopentadienyl from phosphorus to iron
Issue Date: 1986
metadata.ubs.publikation.typ: Zeitschriftenartikel
metadata.ubs.publikation.source: Organometallics 5 (1986), S. 593-595. URL http://dx.doi.org./10.1021/om00134a036
URI: http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-74689
http://elib.uni-stuttgart.de/handle/11682/7999
http://dx.doi.org/10.18419/opus-7982
Abstract: The reaction of the phosphaalkene (μ1-Me5C5)P=C(SiMe3)2 with Fe2(CO)9 affords the μ1 (P-bonded) complex (μ1-Me5C5)[(CO)4Fe]P=C(SiMe3)2 (4). Photolysis of 4 produces the phosphavinyl complex [Fe-{μ1-P=C(SiMe3)2}(η5-Me5C5)(CO)2] (5). Compound 5 can also be prepared via the metathetical reaction of (Me3Si)2C=PCl with K[Fe(η5-Me5C5)(CO)2]. The structure of 5 has been determined by X-ray crystallography.
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