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Autor(en): Effenberger, Franz
Titel: Electrophilic reagents : recent developments and their preparative application
Erscheinungsdatum: 1980
Dokumentart: Zeitschriftenartikel
Erschienen in: Angewandte Chemie, International edition 19 (1980), S. 151-171. URL http://dx.doi.org./10.1002/anie.198001513
URI: http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-42534
http://elib.uni-stuttgart.de/handle/11682/974
http://dx.doi.org/10.18419/opus-957
Zusammenfassung: The most widely known electrophilic agents are protic acids and compounds with an electronsextet partial structure. Recent research has aimed at the development of new electrophilic reagents, with greater reactivity on the one hand and higher selectivity on the other, which would largely obviate the addition of Lewis acids (Friedel-Crafts catalysts), and also allow control of the isomer ratio in reactions with ambivalent substrates. Compounds with super-leaving groups, such as trifluoromethanesulfonate and fluorosulfate, have been demonstrated as most advantageous in this respect since they are sufficiently polarized or dissociated for reactions to take place even in the absence of Friedel-Crafts catalysts. Heterocycles such as pyridones or imidazole are likewise suitable leaving groups; they are employed for their high selectivity, and also because they allow working under non-aqueous conditions.
Enthalten in den Sammlungen:03 Fakultät Chemie

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