Stereoselektive Darstellung von Thiozuckern aus achiralen Vorstufen mittels Enzymen (Enzym-katalysierte Reaktionen ; 14)

Effenberger, Franz; Straub, Alexander; Null, Volker

Stereoselektive Darstellung von Thiozuckern aus achiralen Vorstufen mittels Enzymen (Enzym-katalysierte Reaktionen ; 14)

dc.contributor.author	Effenberger, Franz	de
dc.contributor.author	Straub, Alexander	de
dc.contributor.author	Null, Volker	de
dc.date.accessioned	2009-08-28	de
dc.date.accessioned	2016-03-31T07:47:47Z
dc.date.available	2009-08-28	de
dc.date.available	2016-03-31T07:47:47Z
dc.date.issued	1992	de
dc.description.abstract	A novel synthesis for thiosugars starting from achiral compounds by using enzymes as catalysts is described. 5-Thio-D-threo-2-pentulofuranose (4), for example, is prepared either by the RAMA (rabbit muscle aldolase)-catalyzed reaction of mercaptoacetaldehyde (1b) with dihydroxyacetonephosphate (2) or by the yeast transketolase-catalyzed reaction of 2-hydroxy-3-mercaptopanal (R/S)-6 with lithium 3-hydroxypyruvate (9). 6-Thio-D-arabino-2-hexulopyranose (8a) and 6-thio-L-xylo-2-hexulopyranose (8b) are obtained by the RAMA-catalyzed reaction of racemic (R/S)-6 with 2.	en
dc.identifier.other	316220310	de
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-44387	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/1176
dc.identifier.uri	http://dx.doi.org/10.18419/opus-1159
dc.language.iso	de	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.subject.classification	Thiophenderivate , Transketolase , Enzymkatalyse	de
dc.subject.ddc	540	de
dc.title	Stereoselektive Darstellung von Thiozuckern aus achiralen Vorstufen mittels Enzymen (Enzym-katalysierte Reaktionen ; 14)	de
dc.title.alternative	Stereoselective synthesis of thiosugars from achiral starting compounds by enzymes (Enzyme-catalyzed reactions ; 14)	en
dc.type	article	de
ubs.fakultaet	Fakultät Chemie	de
ubs.institut	Institut für Organische Chemie	de
ubs.opusid	4438	de
ubs.publikation.source	Justus Liebigs Annalen der Chemie (1992), S. 1297-1301. URL http://dx.doi.org./10.1002/jlac.1992199201214	de
ubs.publikation.typ	Zeitschriftenartikel	de

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