Synthesis and characterization of the amidomanganates Rb2[Mn(NH2)4] and Cs2[Mn(NH2)4]
| dc.contributor.author | Bäucker, Christian | |
| dc.contributor.author | Bauch, Soeren | |
| dc.contributor.author | Niewa, Rainer | |
| dc.date.accessioned | 2023-03-30T12:12:30Z | |
| dc.date.available | 2023-03-30T12:12:30Z | |
| dc.date.issued | 2021 | |
| dc.date.updated | 2021-07-03T20:10:22Z | |
| dc.description.abstract | We report the successful synthesis of Rb2[Mn(NH2)4] and Cs2[Mn(NH2)4] from ammonothermal conditions at 723 K and pressures above 850 bar. Both compounds were obtained single phase according to powder X-ray diffraction. The crystal structures were determined by single crystal X-ray diffraction. For Rb2[Mn(NH2)4] we have obtained the high-temperature phase. The structures are analyzed with respect to the earlier reported alkali metal amidomanganates. Upon heating in inert atmosphere Cs2[Mn(NH2)4] decomposes to manganese nitrides. IR spectroscopic results are reported. | en |
| dc.description.sponsorship | Deutsche Forschungsgemeinschaft (DFG) | de |
| dc.identifier.issn | 2073-4352 | |
| dc.identifier.other | 1841487546 | |
| dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-128845 | de |
| dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/12884 | |
| dc.identifier.uri | http://dx.doi.org/10.18419/opus-12865 | |
| dc.language.iso | en | de |
| dc.relation.uri | doi:10.3390/cryst11060676 | de |
| dc.rights | info:eu-repo/semantics/openAccess | de |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | de |
| dc.subject.ddc | 540 | de |
| dc.title | Synthesis and characterization of the amidomanganates Rb2[Mn(NH2)4] and Cs2[Mn(NH2)4] | en |
| dc.type | article | de |
| ubs.fakultaet | Chemie | de |
| ubs.institut | Institut für Anorganische Chemie | de |
| ubs.publikation.seiten | 10 | de |
| ubs.publikation.source | Crystals 11 (2021), No. 676 | de |
| ubs.publikation.typ | Zeitschriftenartikel | de |