On the spin distribution in bridged anthracene-viologen molecules : an electron-nuclear double resonance study

Sariciftci, Serdar; Werner, Andreas; Grupp, Arthur; Mehring, Michael; Götz, Günther; Bäuerle, Peter; Effenberger, Franz

On the spin distribution in bridged anthracene-viologen molecules : an electron-nuclear double resonance study

dc.contributor.author	Sariciftci, Serdar	de
dc.contributor.author	Werner, Andreas	de
dc.contributor.author	Grupp, Arthur	de
dc.contributor.author	Mehring, Michael	de
dc.contributor.author	Götz, Günther	de
dc.contributor.author	Bäuerle, Peter	de
dc.contributor.author	Effenberger, Franz	de
dc.date.accessioned	2009-08-28	de
dc.date.accessioned	2016-03-31T07:47:46Z
dc.date.available	2009-08-28	de
dc.date.available	2016-03-31T07:47:46Z
dc.date.issued	1992	de
dc.description.abstract	Studies on the spin distribution in the radical state of anthracene-σ bridge viologen supermolecules with different bridge units are reported. Electronnuclear double resonance experiments (ENDOR) were performed on electrochemically reduced molecules. Proton hyperfine coupling constants at different molecular sites were obtained and are discussed in detail. The experimentally determined values are compared with quantum chemical calculations of the INDO type. The observed spin distribution depends significantly on the type of the bridging unit. The relevance of the spin distribution for electron transfer in donor-bridge-acceptor molecular complexes is discussed.	en
dc.identifier.other	316188743	de
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-44282	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/1168
dc.identifier.uri	http://dx.doi.org/10.18419/opus-1151
dc.language.iso	en	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.subject.classification	Viologene , ENDOR	de
dc.subject.ddc	540	de
dc.title	On the spin distribution in bridged anthracene-viologen molecules : an electron-nuclear double resonance study	en
dc.type	article	de
ubs.fakultaet	Fakultät Chemie	de
ubs.fakultaet	Fakultät Mathematik und Physik	de
ubs.institut	Institut für Organische Chemie	de
ubs.institut	2. Physikalisches Institut	de
ubs.opusid	4428	de
ubs.publikation.source	Molecular Physics 75 (1992), S. 1259-1267. URL http://dx.doi.org./10.1080/00268979200100961	de
ubs.publikation.typ	Zeitschriftenartikel	de

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