Kinetic instabilities in heterogeneously catalyzed reactions. Pt. 2, Oscillatory instabilities with Langmuir type reactions

dc.contributor.authorEigenberger, Gerhartde
dc.date.accessioned2010-03-08de
dc.date.accessioned2016-03-31T08:16:16Z
dc.date.available2010-03-08de
dc.date.available2016-03-31T08:16:16Z
dc.date.issued1978de
dc.date.updated2010-04-16de
dc.description.abstractAn analysis of the kinetic model studied in Part I of this contribution gave no indication for the occurrance of periodic solutions. However if an additional slow chemisorption ("buffer") step is added to the model, relaxation oscillations can develop in regions where the original model exhibited multiple solutions. The behaviour of the extended model is analysed via the singular perturbation approach and by simulation. It is shown that a broad variety of slow chemisorption steps can serve as buffer with the restriction that the buffer step should not, or at least only slightly, contribute to the surface reaction.en
dc.identifier.other321923286de
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-51533de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/4303
dc.identifier.urihttp://dx.doi.org/10.18419/opus-4286
dc.language.isoende
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationInstabilität , Katalysator , Modellierung , Chemisorptionde
dc.subject.ddc660de
dc.titleKinetic instabilities in heterogeneously catalyzed reactions. Pt. 2, Oscillatory instabilities with Langmuir type reactionsen
dc.typearticlede
ubs.fakultaetFakultät Konstruktions-, Produktions- und Fahrzeugtechnikde
ubs.institutInstitut für Systemtheorie und Regelungstechnikde
ubs.opusid5153de
ubs.publikation.sourceChemical Engineering Science 33 (1978), S. 1263-1268de
ubs.publikation.typZeitschriftenartikelde

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